Rhodium catalyzed C-H olefination of N-benzoylsulfonamides with internal alkenes

被引：141

作者：

Zhu, Chen ^{[1
]}

Falck, John R.

机构：

[1] Univ Texas SW Med Ctr Dallas, Dept Biochem, Dallas, TX 75390 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 11期

关键词：

BOND FORMATION; OXIDATIVE OLEFINATION; INHIBITORS; ALKYNES; ACTIVATION; BENZAMIDES; FUNCTIONALIZATION; DERIVATIVES; CYCLIZATION; PAGOCLONE;

D O I：

10.1039/c2cc16963k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An annulation via tandem rhodium catalyzed C-H olefination of N-benzoylsulfonamides with internal olefins followed by C-N bond formation is disclosed. A N-substituted quaternary center is formed during the reaction thus providing efficient access to a series of 3,3-disubstituted isoindolinones.

引用

页码：1674 / 1676

页数：3

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