Hydrogen Isotope Effects on Aqueous Electrolyte for Electrochemical Lithium-Ion Storage

被引：22

作者：

Chou, Jia ^{[1
,2
]}

Zhao, Yao ^{[2
,3
]}

Li, Xue-Ting ^{[1
,2
]}

Wang, Wen-Peng ^{[1
,2
]}

Tan, Shuang-Jie ^{[1
,2
]}

Wang, Ya-Hui ^{[1
,2
]}

Zhang, Juan ^{[1
,2
]}

Yin, Ya-Xia ^{[1
,2
]}

Wang, Fuyi ^{[2
,3
]}

Xin, Sen ^{[1
,2
]}

Guo, Yu-Guo ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Inst Chem,CAS Key Lab Mol Nanostruct & Nanotechno, Beijing Natl Lab Mol Sci BNLMS, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Beijing Inst Chem, Natl Ctr Mass Spectrometry,CAS Key Lab Analyt Che, BNLMS,CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2022年 / 61卷 / 25期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Aqueous Electrolyte; Deuterium Oxide; Electrochemical Isotope Effects; Hydrogen Bond; Li-Ion Storage; HEAVY-WATER; NEUTRON-DIFFRACTION; LIGHT;

D O I：

10.1002/anie.202203137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As two stable hydrogen isotopes, protium and deuterium show magnified isotope effects in physicochemical properties due to the significantly varied atomic masses. In this work, aqueous electrolytes based on heavy water (D2O) and light water (H2O) were prepared to reveal the electrochemical isotope effects between the hydrogen isotopes. The covalent hydrogen-oxygen bond and intermolecular hydrogen bond in D2O are much stronger than those in H2O, making them thermodynamically more stable. Compared with the H2O-based electrolyte, the D2O-based electrolyte shows a broader electrochemical window, a higher percentage of coordinated water and a longer lifetime of hydrogen bond. Because of the above electrochemical isotope effects, the D2O-based electrolyte shows high anodic stability against operation of high-voltage layered oxide cathode materials including LiCoO2 and LiNi0.8Co0.1Mn0.1O2, which enables long cycle life and favorable rate performance of aqueous Li-ion batteries.

引用

页数：5

共 40 条

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