Long-Range Structures of Amorphous Solid Water

被引:14
作者
Li, Hailong [1 ]
Karina, Aigerim [1 ]
Ladd-Parada, Marjorie [1 ]
Spah, Alexander [1 ]
Perakis, Fivos [1 ]
Benmore, Chris [2 ]
Amann-Winkel, Katrin [1 ,3 ,4 ]
机构
[1] Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden
[2] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA
[3] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[4] Johannes Gutenberg Univ Mainz, Inst Phys, D-55128 Mainz, Germany
关键词
X-RAY; INFRARED-SPECTROSCOPY; STACKING DISORDER; BENDING MODE; CUBIC ICE; DENSITY; FORMS; CRYSTALLIZATION; IRRADIATION; COMPACTION;
D O I
10.1021/acs.jpcb.1c06899
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-energy X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) of amorphous solid water (ASW) were studied during vapor deposition and the heating process. From the diffraction patterns, the oxygen-oxygen pair distribution functions (PDFs) were calculated up to the eighth coordination shell and an r = 23 angstrom. The PDF of ASW obtained both during vapor deposition at 80 K as well as the subsequent heating are consistent with that of low-density amorphous ice. The formation and temperature-induced collapse of micropores were observed in the XRD data and in the FTIR measurements, more specifically, in the OH stretch and the dangling mode. Above 140 K, ASW crystallizes into a stacking disordered ice, I-sd. It is observed that the fourth, fifth, and sixth peaks in the PDF, corresponding to structural arrangements between 8 and 12 angstrom, are the most sensitive to the onset of crystallization.
引用
收藏
页码:13320 / 13328
页数:9
相关论文
共 71 条
[1]   X-ray and Neutron Scattering of Water [J].
Amann-Winkel, Katrin ;
Bellissent-Funel, Marie-Claire ;
Bove, Livia E. ;
Loerting, Thomas ;
Nilsson, Anders ;
Paciaroni, Alessandro ;
Schlesinger, Daniel ;
Skinner, Lawrie .
CHEMICAL REVIEWS, 2016, 116 (13) :7570-7589
[2]   Colloquium: Water's controversial glass transitions [J].
Amann-Winkel, Katrin ;
Boehmer, Roland ;
Fujara, Franz ;
Gainaru, Catalin ;
Geil, Burkhard ;
Loerting, Thomas .
REVIEWS OF MODERN PHYSICS, 2016, 88 (01)
[3]   AMORPHOUS WATER ICE AND ITS ABILITY TO TRAP GASES [J].
BARNUN, A ;
DROR, J ;
KOCHAVI, E ;
LAUFER, D .
PHYSICAL REVIEW B, 1987, 35 (05) :2427-2435
[4]   Thermal collapse of porous interstellar ice [J].
Bossa, J. -B. ;
Isokoski, K. ;
de Valois, M. S. ;
Linnartz, H. .
ASTRONOMY & ASTROPHYSICS, 2012, 545
[5]   The local and intermediate range structures of the five amorphous ices at 80 K and ambient pressure: A Faber-Ziman and Bhatia-Thornton analysis [J].
Bowron, D. T. ;
Finney, J. L. ;
Hallbrucker, A. ;
Kohl, I. ;
Loerting, T. ;
Mayer, E. ;
Soper, A. K. .
JOURNAL OF CHEMICAL PHYSICS, 2006, 125 (19)
[6]  
Burton E. F., 1975, PHYS B, V26, P211
[7]   X-ray diffraction patterns of ice [J].
Burton, EF ;
Oliver, WF .
NATURE, 1935, 135 :505-506
[8]   THE MESOSCALE MORPHOLOGIES OF ICE FILMS: POROUS AND BIOMORPHIC FORMS OF ICE UNDER ASTROPHYSICAL CONDITIONS [J].
Cartwright, Julyan H. E. ;
Escribano, Bruno ;
Ignacio Sainz-Diaz, C. .
ASTROPHYSICAL JOURNAL, 2008, 687 (02) :1406-1414
[9]   Infrared Spectroscopy and Optical Constants of Porous Amorphous Solid Water [J].
Cholette, Francois ;
Zubkov, Tykhon ;
Smith, R. Scott ;
Dohnalek, Zdenek ;
Kay, Bruce D. ;
Ayotte, Patrick .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (13) :4131-4140
[10]   Radiolysis of astrophysical ices by heavy ion irradiation: Destruction cross section measurement [J].
de Barros, A. L. F. ;
Boduch, P. ;
Domaracka, A. ;
Rothard, H. ;
da Silveira, E. F. .
LOW TEMPERATURE PHYSICS, 2012, 38 (08) :759-765