Cage-opening supramolecular isomerism in Cu(II) complexes

被引：4

作者：

Yu, Hui-Juan ^{[1
]}

Liu, Zhi-Min ^{[2
]}

Yin, Shao-Yun ^{[1
]}

Wu, Kai ^{[1
]}

Wei, Zhang-Wen ^{[1
]}

Pan, Mei ^{[1
]}

机构：

[1] Sun Yat Sen Univ, MOE Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Lehn Inst Funct Mat,Sch Chem, Guangzhou 510275, Guangdong, Peoples R China

[2] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 86卷

关键词：

METAL-ORGANIC FRAMEWORKS; MOLECULES;

D O I：

10.1016/j.inoche.2017.10.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Cu(NO3)(2)center dot 3H(2)O or Cu(CF3SO3)(2)center dot 6H(2)O with semirigid ligands 2,6-bis(pyridin-3-ylmethyl)-3a,4,4a,7a,8,8a-hexahydro-4,8-ethenopyrrolo[3,4-fjisoindole-1,3,5,7(2H,6H)-tetraone (L1) and 2,6-bis(pyridin-4-ylmethyl)-3a,4,4a,7a,8,8a-hexahydro-4,8-ethenopyrrolo[3,4-flisoindole-1,3,5,7(2H,6H)-tetraone (12) result in OD tetragonal prismatic cage (1,4), 1D loop-and-chain (2, 5, 6), and 2D (4,4) network (3) metal-organic complexes, which comprise of U-a, U-b Or Z type ligand conformations, respectively. Solid state X-ray diffraction and solution state ESI-MS analyses manifest the ring-opening isomerization mechanism among the complexes, and photoluminescence properties are also studied. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：223 / 226

页数：4

共 50 条

[1] Fullerene peroxides in cage-opening reactions
Gan, LB
PURE AND APPLIED CHEMISTRY, 2006, 78 (04) : 841 - 845
[2] CHROMIUM CLUSTER COMPLEXES FROM CAGE-OPENING OF POLYCHALCOGEN-PNICOGEN MOLECULES
GOH, LY
WEI, C
WONG, RCS
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1994, 93 (1-4): : 209 - 212
[3] Chromium Cluster Complexes from Cage-Opening of Polychalcogen-Pnicogen Molecules
Goh, L. Y.
Wei, C.
Wong, R. C. S.
Phosphorus, Sulphur and Silicon and the Related Elements, 1994, 93 (1-4):
[4] Transition metal catalyzed epoxidation and cage-opening of fullerenes
Anderson, Robin E.
Barron, Andrew R.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[5] Synthesis of a green [60]fullerene derivative through cage-opening reactions
Liu, Shuming
Zhang, Changqi
Xie, Xiang
Yu, Yuming
Dai, Zhifei
Shao, Yuanhua
Gan, Liangbing
Li, Yuliang
CHEMICAL COMMUNICATIONS, 2012, 48 (19) : 2531 - 2533
[6] Synthesis of Strongly Fluorescent Graphene Quantum Dots by Cage-Opening Buckminsterfullerene
Chua, Chun Kiang
Sofer, Zdenek
Simek, Petr
Jankovsky, Ondrej
Klimova, Katerina
Bakardjieva, Snejana
Kuckova, Stepanka Hrdlickova
Pumera, Martin
ACS NANO, 2015, 9 (03) : 2548 - 2555
[7] New copper(II) halogenobenzoate complexes with nicotinamide: isomerism and supramolecular structure
Moncol, Jan
Halaska, Jozef
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2015, 71 : S428 - S428
[8] Efficient Cage-Opening Cascade Process for the Preparation of Water-Encapsulated [60]Fullerene Derivatives
Zhang, Qianyan
Jia, Zhenshan
Liu, Shuming
Zhang, Gang
Xiao, Zuo
Yang, Dazhi
Gan, Liangbing
Wang, Zheming
Li, Yuliang
ORGANIC LETTERS, 2009, 11 (13) : 2772 - 2774
[9] Influence of ligand positional isomerism on the molecular and supramolecular structures of cobalt( II)-phenylimidazole complexes
Duros, Vasilios
Papatriantafyllopoulou, Constantina
Kitos, Alexandors A.
Tasiopoulos, Anastasios J.
Nastopoulos, Vassilios
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2019, 75 : 599 - 610
[10] Regioselective thermal cage-opening reactions of 4-amino substituted 1,3-bishomocubanones
Bakkeren, FJAD
Schröer, F
Klunder, AJH
Zwanenburg, B
TETRAHEDRON LETTERS, 1998, 39 (51) : 9531 - 9534

← 1 2 3 4 5 →