Photocatalytic Activity of Nonprecious Metal WSe2/g-C3N4 Composite Under Visible Light Irradiation

被引:7
作者
Wang, Jieqiong [1 ,2 ]
Yang, Jie [1 ]
Fang, Jian [1 ]
Li, Yuhang [1 ]
Zhang, Hongyuan [1 ]
Zhao, Zhenbo [1 ]
Ao, Yuhui [1 ]
机构
[1] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Jilin, Peoples R China
[2] Changchun Univ Technol, Jilin Prov Key Lab Carbon Fiber Dev & Applicat, Changchun 130012, Jilin, Peoples R China
关键词
g-C3N4; WSe2; hydrothermal method; photocatalytic degradation; methyl orange; GRAPHITIC CARBON NITRIDE; HYDROGEN-EVOLUTION; ORGANIC-DYES; RHODAMINE-B; DEGRADATION; G-C3N4; NANOSHEETS; COCATALYST; GRAPHENE; WSE2;
D O I
10.1142/S1793292020500423
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The WSe2/g-C3N4 (graphite carbon nitride) composite with photocatalytic properties was synthesized using a hydrothermal method. This synthesis pathway can be characterized by being simple, inexpensive and nonpolluting, integrating the concept of green chemistry. The WSe2/g-C3N4 composite could effectively degrade methyl orange solution under visible light irradiation. The decolorization experiment of methyl orange solution shows that the degradation rate of the 30 wt.% WSe2/g-C3N4 composite can reach 98.7% after 100 min of illumination, while the degradation rate of pure g-C3N4 was only 87.6% under the same conditions. This can be attributed to the fact that the combination of WSe2 and g-C3N4 nanosheets can increase the number of active binding sites, increasing the rate of charge separation and transport ability, decreasing the recombination rate of the photogenerated electron-hole pairs. Therefore, the WSe2/g-C3N4 composite will have potential development as a new material with low cost, easy synthesis and excellent performance in photocatalytic degradation of water pollution.
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页数:12
相关论文
共 63 条
[1]   Surface Analysis of WSe2 Crystals: Spatial and Electronic Variability [J].
Addou, Rafik ;
Wallace, Robert M. .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (39) :26400-26406
[2]   Photocatalytic degradation of Rhodamine B over a novel mesoporous titanosilicate/g-C3N4 nanocomposite under direct sunlight irradiation [J].
Adepu, Ajay Kumar ;
Anumula, Rajini ;
Narayanan, Venkatathri .
MICROPOROUS AND MESOPOROUS MATERIALS, 2017, 247 :86-94
[3]   Enhanced visible light photocatalytic H2-production of g-C3N4/WS2 composite heterostructures [J].
Akple, Maxwell Selase ;
Low, Jingxiang ;
Wageh, S. ;
Al-Ghamdi, Ahmed. A. ;
Yu, Jiaguo ;
Zhang, Jun .
APPLIED SURFACE SCIENCE, 2015, 358 :196-203
[4]   Novel magnetically separable Fe3O4-WSe2/NG photocatalysts: synthesis and photocatalytic performance under visible-light irradiation [J].
An, Baihong ;
Liu, Yanan ;
Xu, Chengcheng ;
Wang, Han ;
Wan, Jun .
NEW JOURNAL OF CHEMISTRY, 2018, 42 (11) :8914-8923
[5]  
Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/NCHEM.1589, 10.1038/nchem.1589]
[6]   Synthesis of magnetic-photo-Fenton catalyst for degradation of emerging pollutant [J].
Diez, A. M. ;
Pazos, M. ;
Sanroman, M. A. .
CATALYSIS TODAY, 2019, 328 :267-273
[7]   Fragmented phosphorus-doped graphitic carbon nitride nanoflakes with broad sub-bandgap absorption for highly efficient visible-light photocatalytic hydrogen evolution [J].
Fang, Hua-Bin ;
Zhang, Xiao-Hong ;
Wu, Jiaojiao ;
Li, Nan ;
Zheng, Yan-Zhen ;
Tao, Xia .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 225 :397-405
[8]   Enhanced visible light photocatalytic activity of novel polymeric g-C3N4 loaded with Ag nanoparticles [J].
Ge, Lei ;
Han, Changcun ;
Liu, Jing ;
Li, Yunfeng .
APPLIED CATALYSIS A-GENERAL, 2011, 409 :215-222
[9]   Two-Step Growth of Two-Dimensional WSe2/MoSe2 Heterostructures [J].
Gong, Yongji ;
Lei, Sidong ;
Ye, Gonglan ;
Li, Bo ;
He, Yongmin ;
Keyshar, Kunttal ;
Zhang, Xiang ;
Wang, Qizhong ;
Lou, Jun ;
Liu, Zheng ;
Vajtai, Robert ;
Zhou, Wu ;
Ajayan, Pulickel M. .
NANO LETTERS, 2015, 15 (09) :6135-6141
[10]   Atomically thin MoSe2/graphene and WSe2/graphene nanosheets for the highly efficient oxygen reduction reaction [J].
Guo, Jiahao ;
Shi, Yantao ;
Bai, Xiaogong ;
Wang, Xuchun ;
Ma, Tingli .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (48) :24397-24404