Clouding of nonionic surfactants

被引：90

作者：

Lindman, Bjorn ^{[1
,2
,3
,4
]}

Medronho, Bruno ^{[5
]}

Karlstrom, Gunnar ^{[6
]}

机构：

[1] Univ Coimbra, Dept Chem, P-3004535 Coimbra, Portugal

[2] Lund Univ, Div Phys Chem, Ctr Chem & Chem Engn, Dept Chem, SE-22100 Lund, Sweden

[3] Nanyang Technol Univ, Mat Sci & Engn, Singapore 639798, Singapore

[4] Mid Sweden Univ, FSCN, SE-85170 Sundsvall, Sweden

[5] Univ Algarve, Fac Sci & Technol MEDITBIO, Campus Gambelas,Ed 8, P-8005139 Faro, Portugal

[6] Lund Univ, Div Theoret Chem, Dept Chem, Ctr Chem & Chem Engn, SE-22100 Lund, Sweden

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2016年 / 22卷

基金：

瑞典研究理事会;

关键词：

Nonionic surfactant; Clouding; Oxyethylene; Micelle growth; Phase separation; RESONANCE SELF-DIFFUSION; SOLID-STATE NMR; AQUEOUS-SOLUTIONS; PHASE-BEHAVIOR; POLY(ETHYLENE OXIDE); MICELLAR-SOLUTIONS; NONAQUEOUS SOLUTION; MOLECULAR-DYNAMICS; LIGHT-SCATTERING; SODIUM-CHLORIDE;

D O I：

10.1016/j.cocis.2016.01.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nonionic surfactants have broad applications such as cleaning and dispersion stabilization, which frequently are hampered by strong temperature sensitivities. As manifested by clouding and decreased solubility with increasing temperature, the interaction between water and the oligo(oxyethylene) head-groups is becoming less favorable. Different aspects of surfactant self-assembly, like the critical micelle concentration, micelle size and shape, intermicellar interactions and phase separation phenomena are reviewed as well as suggested underlying causes of the temperature dependence. Furthermore, the effect of cosolutes on clouding and the behavior of related systems, non-aqueous solutions and nonionic polymers, are examined. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：23 / 29

页数：7

共 43 条

[1] DYNAMICS AND ORDER OF NONIONIC SURFACTANTS IN NEAT LIQUID AND MICELLAR SOLUTION FROM MULTIFIELD C-13 NMR RELAXATION AND C-13 NMR CHEMICAL-SHIFTS [J].

AHLNAS, T ;

KARLSTROM, G ;

LINDMAN, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (15) :4030-4036

[2] CONFORMATIONAL STRUCTURE OF 1,2-DIMETHOXYETHANE IN WATER AND OTHER DIPOLAR SOLVENTS, STUDIED BY QUANTUM CHEMICAL, REACTION FIELD, AND STATISTICAL MECHANICAL TECHNIQUES [J].

ANDERSSON, M ;

KARLSTROM, G .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (23) :4957-4962

[3] Micellar growth, network formation, and criticality in aqueous solutions of the nonionic surfactant C12E5 [J].

Bernheim-Groswasser, A ;

Wachtel, E ;

Talmon, Y .

LANGMUIR, 2000, 16 (09) :4131-4140

[4] AGGREGATION BEHAVIOR AND MICELLAR DYNAMICS IN AQUEOUS-SOLUTIONS OF THE NONIONIC SURFACTANT PENTAOXYETHYLENEGLYCOL MONOOCTYL ETHER - EFFECT OF SODIUM-HALIDES [J].

BINANALIMBELE, W ;

VANOS, NM ;

RUPERT, LAM ;

ZANA, R .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1991, 144 (02) :458-467

[5]

BJORLING M, 1991, J PHYS CHEM-US, V95, P6706, DOI 10.1021/j100170a060

[6] SIZE AND SHAPE OF NON-IONIC AMPHIPHILE (C12E6) MICELLES IN DILUTE AQUEOUS-SOLUTIONS AS DERIVED FROM QUASIELASTIC AND INTENSITY LIGHT-SCATTERING, SEDIMENTATION, AND PULSED-FIELD-GRADIENT NUCLEAR MAGNETIC-RESONANCE SELF-DIFFUSION DATA [J].

BROWN, W ;

JOHNSEN, R ;

STILBS, P ;

LINDMAN, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (22) :4548-4553

[7] SYNERGISTIC SURFACTANT ELECTROLYTE EFFECT IN POLYMER-SOLUTIONS [J].

CARLSSON, A ;

KARLSTROM, G ;

LINDMAN, B .

LANGMUIR, 1986, 2 (04) :536-537

[8] Aggregation and microstructure in aqueous solutions of the nonionic surfactant C(12)E(8) [J].

Danino, D ;

Talmon, Y ;

Zana, R .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 186 (01) :170-179

[9] Molecular Conformation and Bilayer Pores in a Nonionic Surfactant Lamellar Phase Studied with 1H-13C Solid-State NMR and Molecular Dynamics Simulations [J].

Ferreira, Tiago M. ;

Topgaard, Daniel ;

Ollila, O. H. Samuli .

LANGMUIR, 2014, 30 (02) :461-469

[10] Segmental order parameters in a nonionic surfactant lamellar phase studied with 1H-13C solid-state NMR [J].

Ferreira, Tiago Mendes ;

Medronho, Bruno ;

Martin, Rachel W. ;

Topgaard, Daniel .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (39) :6033-6038

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