Revelation of ion hydration in Raman scattering spectral bands of water

被引:22
作者
Burikov, S. A.
Dolenko, T. A.
Fadeev, V. V.
Vlasov, I. I.
机构
[1] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119992, Russia
[2] Russian Acad Sci, Ctr Nat Sci, Inst Gen Phys, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S1054660X0710012X
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The influence of ions with different hydration properties on the stretching, bending, and low-frequency bands of water Raman scattering spectra has been investigated. The obtained results are explained using the ion hydration theory: from the point of view of the formation of hydration shells, ion pairs and complexes, and the migration of protons in water. Using the detected peculiarities of the dependences of spectra characteristics on the salt concentration for the determination of the parameters of long-range and short-range hydration is proposed.
引用
收藏
页码:1255 / 1261
页数:7
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