Revelation of ion hydration in Raman scattering spectral bands of water

被引：22
作者：
Burikov, S. A.
Dolenko, T. A.
Fadeev, V. V.
Vlasov, I. I.
机构：
[1] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119992, Russia
[2] Russian Acad Sci, Ctr Nat Sci, Inst Gen Phys, Moscow 119991, Russia
来源：
LASER PHYSICS | 2007年 / 17卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S1054660X0710012X
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The influence of ions with different hydration properties on the stretching, bending, and low-frequency bands of water Raman scattering spectra has been investigated. The obtained results are explained using the ion hydration theory: from the point of view of the formation of hydration shells, ion pairs and complexes, and the migration of protons in water. Using the detected peculiarities of the dependences of spectra characteristics on the salt concentration for the determination of the parameters of long-range and short-range hydration is proposed.
引用
收藏
页码：1255 / 1261
页数：7
相关论文
共 16 条
[1]   ASSESSMENT OF CORRECTION PROCEDURES FOR REDUCTION OF RAMAN-SPECTRA [J].
BROOKER, MH ;
NIELSEN, OF ;
PRAESTGAARD, E .
JOURNAL OF RAMAN SPECTROSCOPY, 1988, 19 (02) :71-78
[2]   About the possibility of determination of ions hydration parameters by Raman spectroscopy [J].
Burikov, SA ;
Barinova, NE ;
Dolenko, TA ;
Sugonjaev, AV .
OPTO-IRELAND 2005: OPTICAL SENSING AND SPECTROSCOPY, 2005, 5826 :281-289
[3]   The effect of hydration of ions of inorganic salts on the shape of the Raman stretching band of water [J].
Burikov, SA ;
Dolenko, TA ;
Velikotnyi, PA ;
Sugonyaev, AV ;
Fadeev, VV .
OPTICS AND SPECTROSCOPY, 2005, 98 (02) :235-239
[4]  
CHAPLIN M, WATER STRUCTURE BEHA
[5]  
Dolenko TA, 2000, J RAMAN SPECTROSC, V31, P863, DOI 10.1002/1097-4555(200008/09)31:8/9<863::AID-JRS630>3.0.CO
[6]  
2-C
[7]  
KNUNJANC IL, 1967, BRIEF CHEM ENCY, V5
[8]   X-RAY DIFFRACTION STUDIES OF AQUEOUS ALKALI-METAL HALIDE SOLUTIONS [J].
LAWRENCE, RM ;
KRUH, RF .
JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (11) :4758-&
[9]   RAMAN-SPECTRA OF WATER IN RARE-EARTH CHLORIDE SOLUTIONS [J].
MUNDY, WC ;
SPEDDING, FH .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (05) :2183-2190
[10]   ANTI-STOKES LOW-FREQUENCY RAMAN-SPECTRA OF LIQUIDS [J].
NIELSEN, OF .
JOURNAL OF RAMAN SPECTROSCOPY, 1989, 20 (04) :221-225
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