Highly concentrated emulsions as novel reaction media

被引：14
|
作者：
Solans, C [1 ]
Pinazo, A [1 ]
Calderó, G [1 ]
Infante, MR [1 ]
机构：
[1] CSIC, IIQAB, Dept Tecnol Tensioactius, ES-08034 Barcelona, Spain
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2001年 / 176卷 / 01期
关键词：
concentrated emulsion; water-in-oil emulsion; HIPRE; reactivity; surfactant; lipoaminoacid;
D O I：
10.1016/S0927-7757(00)00616-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Synthesis of a cationic surfactant, N-a-lauroyl arginine methyl ester hydrochloride (LAM) has been carried out in gel emulsions of the system water/C14E4/decane. The yields of LAM synthesized in gel emulsions are comparable to those obtained in conventional dimethylformamide (DMF) media. The rate of LAM formation is faster in gel emulsions at short times, the reaction taking place without mechanical energy input and at 25 degreesC. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：101 / 108
页数：8
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