Linear uranium metallocenes with polydentate aromatic nitrogen ligands

被引：15

作者：

Berthet, Jean-Claude ^{[1
]}

Maynadie, Jerome ^{[1
]}

Thuery, Pierre ^{[1
]}

Ephritikhine, Michel ^{[1
]}

机构：

[1] CEA, CEA CNRS SIS2M, DSM IRAMIS, UMR 3299, F-91191 Gif Sur Yvette, France

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 29期

关键词：

LANTHANIDE(III)/ACTINIDE(III) DIFFERENTIATION; CRYSTAL-STRUCTURES; TRIS(CYCLOPENTADIENYL) COMPLEXES; SELECTIVE COMPLEXATION; COORDINATION; 2,2'/6',2''-TERPYRIDINE; SEPARATION; CERIUM; BENT; LANTHANIDES(III);

D O I：

10.1039/c002279a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Cp-2*U(NCMe)(5)]X-2 [Cp* = C5Me5, X = BPh4 (1) or I (1')] or Cp-2*UI2 in acetonitrile with the polydentate aromatic nitrogen bases phen, terpy and R(4)btbp led to the formation of the linear uranium metallocenes [Cp-2*U(NCMe)(3)(phen)]X-2 [X = BPh4 (2), I (2')], [Cp-2*U(NCMe)(2)(terpy)][BPh4](2) (4), [Cp-2*U(NCMe)(Me(4)btbp)][BPh4](2) (5) and [Cp-2*U(NCMe)(CyMe(4)btbp)][X](2), [X = BPh4 (6), I (6')], [phen = 1,10-phenanthroline, terpy = 2,2':6,2 ''-terpyridine, Me(4)btbp = 6,6'-bis-(3,3,6,6-tetramethyl-1,2,4-triazin-3-yl)-2,2'-bipyridine, CyMe(4)btbp = 6,6'-bis-(3,3,6,6-tetramethyl-cyclohexane-1,2,4-triazin-3-yl)-2,2'-bipyridine]. The bent metallocene [Cp-2*U(phen)(2)][BPh4](2) (3) was isolated from the reaction of 1 and two molar equivalents of phen in THF. The X-ray crystal structures of 2 center dot 2MeCN, 3 center dot 2THF, 4 and 6'center dot 2MeCN were determined.

引用

页码：6801 / 6807

页数：7

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