Activating needle coke to develop anode catalyst for direct methanol fuel cell
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作者:
Park, Young Hun
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Chungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Park, Young Hun
[1
]
Im, Ui-Su
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Univ Sci & Technol, Adv Energy Technol, Daejeon 34113, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Im, Ui-Su
[2
]
Lee, Byung-Rok
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Korea Inst Energy Res, New & Renewable Energy Res Div, Daejeon 34129, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Lee, Byung-Rok
[3
]
Peck, Dong-Hyun
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Korea Inst Energy Res, New & Renewable Energy Res Div, Daejeon 34129, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Peck, Dong-Hyun
[3
]
Kim, Sang-Kyung
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Korea Inst Energy Res, New & Renewable Energy Res Div, Daejeon 34129, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Kim, Sang-Kyung
[3
]
Rhee, Young Woo
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Chungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Rhee, Young Woo
[1
]
Jung, Doo-Hwan
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Univ Sci & Technol, Adv Energy Technol, Daejeon 34113, South Korea
Korea Inst Energy Res, New & Renewable Energy Res Div, Daejeon 34129, South KoreaChungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
Jung, Doo-Hwan
[2
,3
]
机构:
[1] Chungnam Natl Univ, Grad Sch Energy Sci & Technol, Dept Energy Sci & Technol, Daejeon 34134, South Korea
[2] Univ Sci & Technol, Adv Energy Technol, Daejeon 34113, South Korea
[3] Korea Inst Energy Res, New & Renewable Energy Res Div, Daejeon 34129, South Korea
Physical and electrochemical qualities were analyzed after KOH activation of a direct methanol fuel cell using needle coke as anode supporter. The results of research on support loaded with platinum-ruthenium suggest that an activated KOH needle coke container has the lowest onset potential and the highest degree of catalyst activity among all commercial catalysts. Through an analysis of the CO stripping voltammetry, we found that KOH activated catalysis showed a 21% higher electrochemical active surface area (ECSA), with a value of 31.37 m(2)/g, than the ECSA of deactivated catalyst (25.82 m(2)/g). The latter figure was 15% higher than the value of one specific commercial catalyst (TEC86E86).