The fire retardant effects of huntite in natural mixtures with hydromagnesite

被引:51
作者
Hollingbery, L. A. [1 ,2 ]
Hull, T. R. [2 ]
机构
[1] Minelco Ltd, Derby DE21 7BE, England
[2] Univ Cent Lancashire, Ctr Fire & Hazard Sci, Sch Forens & Invest Sci, Preston PR1 2HE, Lancs, England
关键词
Hydromagnesite; Huntite; Fire; Flame; Retardant; Filler; ETHYLENE-VINYL ACETATE; THERMAL-DECOMPOSITION; SYNTHETIC HYDROMAGNESITE; MECHANICAL-PROPERTIES; MAGNESIUM-HYDROXIDE; FLAME RETARDANTS; BEHAVIOR; COMBUSTION; STABILITY;
D O I
10.1016/j.polymdegradstab.2012.01.024
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The fire retardant effects of natural mixtures of huntite and hydromagnesite have been investigated. As well as being entirely natural these mixtures of minerals can be considered "greener" and more environmentally friendly in their production methods than alternatives such as aluminium hydroxide and magnesium hydroxide. It has been shown that the release of water and carbon dioxide from hydromagnesite helps to increase the time to ignition and peak heat release in cone calorimeter testing. Huntite has been shown to decrease the average rate of heat release and increase the strength of the residue. Electron microscopy has shown that the huntite particles maintain their platy morphology during combustion in the cone calorimeter. The morphology of these particles helps to reduce the rate of heat release by slowing the release of flammable decomposition products to the flame. The platy shape of the huntite particles increases the strength of the residue containing higher proportions of this mineral. Huntite is shown to play an active part in improving fire retardancy when used in a mixture with hydromagnesite, giving performance for typical mixtures comparable to those of aluminium hydroxide. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:504 / 512
页数:9
相关论文
共 56 条
[1]  
[Anonymous], 1996, INT J POLYM ANAL CH, DOI DOI 10.1080/10236669608233909
[2]  
Anthony J.W., Handbook of Mineralogy
[3]  
Bariand P., 1973, MINERAL REC, V4, P18
[4]   Influence of Magnesium Hydroxide and Huntite Hydromagnesite on Mechanical Properties of Ethylene Vinyl Acetate Compounds Cross-linked by DiCumyl Peroxide and Ionizing Radiation [J].
Basfar, A. A. ;
Bae, H. J. .
JOURNAL OF FIRE SCIENCES, 2010, 28 (02) :161-180
[5]  
BECK CW, 1950, AM MINERAL, V35, P985
[6]  
Bensalem A, 1999, US Patent, Patent No. [5,979,461, 5979461]
[7]  
Bensalem A, 1999, US Patent, Patent No. [5,927,288, 5927288]
[8]  
Bolger R., 1996, Industrial Minerals, P29
[9]   DTA and FT-IR analysis of the rehydration of basic magnesium carbonate [J].
Botha, A ;
Strydom, CA .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 71 (03) :987-995
[10]  
BRIGGS C, 1990, PLASTICS IN THE ENVIRONMENT : YESTERDAY, TODAY & TOMORROW, P1216