A mixed-valence coordination polymer featuring two-dimensional ferroelectric order:: {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeC4)}n (Et2dtc- = diethyidithiocarbamate)

被引：116

作者：

Okubo, T

Kawajiri, R

Mitani, T

Shimoda, T

机构：

[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan

[2] SEIKO EPSON Corp, Technol Platform Res Ctr, Nagano, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 50期

关键词：

D O I：

10.1021/ja056030p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first mixed-valence coordination polymer indicating ferroelectric properties, {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeCl4)}n (Et2dtc- = diethyldithiocarbamate), has been synthesized and crystallographically characterized. This complex has a two-dimensional infinite square lattice structure, including both Cu(I) and Cu(II) ions, which is confirmed by XPS and SQUID measurements. In addition, the ferroelectric behaviors are revealed by the dielectric measurements with a LCR meter and a ferroelectric tester. Copyright © 2005 American Chemical Society.

引用

页码：17598 / 17599

页数：2

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