A highly active molybdenum multisulfide electrocatalyst for the hydrogen evolution reaction

被引:8
作者
Zhang, Li-Fang [1 ,2 ]
Ou, Gang [2 ]
Gu, Liu [3 ]
Peng, Zhi-Jian [3 ]
Wang, Lu-Ning [1 ,4 ]
Wu, Hui [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[3] China Univ Geosci, Sch Engn & Technol, Beijing 100083, Peoples R China
[4] Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
关键词
EDGE SITES; MOS2; EFFICIENT; CATALYSTS; GRAPHENE; DESIGN; DIOXIDE; OXYGEN;
D O I
10.1039/c6ra18106f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We prepared a highly active molybdenum multisulfide (MoSx) hybrid material by an arc-melting method, which exhibits superior activity in acid media with a low overpotential of 156 mV at j = 10 mA cm(-2), and a Tafel slope of 58 mV dec(-1), surpassing most existing molybdenum-sulfide-based catalysts.
引用
收藏
页码:107158 / 107162
页数:5
相关论文
共 49 条
[31]   Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water [J].
Merki, Daniel ;
Fierro, Stephane ;
Vrubel, Heron ;
Hu, Xile .
CHEMICAL SCIENCE, 2011, 2 (07) :1262-1267
[32]   Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution [J].
Morales-Guio, Carlos G. ;
Stern, Lucas-Alexandre ;
Hu, Xile .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (18) :6555-6569
[33]   Arc-Melting to Narrow the Bandgap of Oxide Semiconductors [J].
Ou, Gang ;
Li, Dongke ;
Pan, Wei ;
Zhang, Qinghua ;
Xu, Ben ;
Gu, Lin ;
Nan, Cewen ;
Wu, Hui .
ADVANCED MATERIALS, 2015, 27 (16) :2589-2594
[34]   Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles** [J].
Popczun, Eric J. ;
Read, Carlos G. ;
Roske, Christopher W. ;
Lewis, Nathan S. ;
Schaak, Raymond E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (21) :5427-5430
[35]   Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces [J].
Stamenkovic, Vojislav R. ;
Mun, Bongjin Simon ;
Arenz, Matthias ;
Mayrhofer, Karl J. J. ;
Lucas, Christopher A. ;
Wang, Guofeng ;
Ross, Philip N. ;
Markovic, Nenad M. .
NATURE MATERIALS, 2007, 6 (03) :241-247
[36]  
Staszak-Jirkovsky J, 2016, NAT MATER, V15, P197, DOI [10.1038/NMAT4481, 10.1038/nmat4481]
[37]   Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0-14 [J].
Tian, Jingqi ;
Liu, Qian ;
Asiri, Abdullah M. ;
Sun, Xuping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (21) :7587-7590
[38]   Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions [J].
Vrubel, Heron ;
Hu, Xile .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (51) :12703-12706
[39]   Solar Water Splitting Cells [J].
Walter, Michael G. ;
Warren, Emily L. ;
McKone, James R. ;
Boettcher, Shannon W. ;
Mi, Qixi ;
Santori, Elizabeth A. ;
Lewis, Nathan S. .
CHEMICAL REVIEWS, 2010, 110 (11) :6446-6473
[40]   Transition-metal doped edge sites in vertically aligned MoS2 catalysts for enhanced hydrogen evolution [J].
Wang, Haotian ;
Tsai, Charlie ;
Kong, Desheng ;
Chan, Karen ;
Abild-Pedersen, Frank ;
Norskov, Jens K. ;
Cui, Yi .
NANO RESEARCH, 2015, 8 (02) :566-575