Asymmetric syntheses of (-)-epi-pseudoconhydrine and (-)-5-hydroxysedamine based on a cis-diastereoselective 1,4-asymmetric induction

被引：15
作者：
Liu, Gang
Meng, Jie
Feng, Chen-Guo
Huang, Pei-Qiang [1 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian, Peoples R China
来源：
TETRAHEDRON-ASYMMETRY | 2008年 / 19卷 / 11期
关键词：
D O I：
10.1016/j.tetasy.2008.05.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The asymmetric syntheses of (-)-epi-pseudoconhydrine and (-)-5-hydroxysedamine are reported. The key to these syntheses is an unusual highly cis-diastereoselective 1,4-asymmetric induction in the alpha-amidoallylation of the new chiral building block 15. (C) 2008 Elsevier Ltd. All rights reserved.
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页码：1297 / 1303
页数：7
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