Locust Bean Gum as a green and novel corrosion inhibitor for Q235 steel in 0.5 M H2SO4 medium

被引:134
作者
Guo, Lei [1 ]
Zhang, Ruilai [3 ]
Tan, Bochuan [2 ]
Li, Wenpo [2 ]
Liu, Hongyan [4 ]
Wu, Sizhan [1 ]
机构
[1] Tongren Univ, Sch Mat & Chem Engn, Tongren 554300, Peoples R China
[2] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China
[3] Chongqing Acad Metrol & Qual Inspect, Chongqing 401123, Peoples R China
[4] Shanxi Datong Univ, Coll Chem & Environm Engn, Datong 037009, Shanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Q235; steel; Locust Bean Gum; Corrosion inhibitor; EIS; Langmuir adsorption; NETTLE LEAVES EXTRACT; MILD-STEEL; COPPER CORROSION; CARBON-STEEL; SULFURIC-ACID; ANTICORROSIVE MECHANISM; MOLECULAR-DYNAMICS; CHLORIDE SOLUTION; 3.5-PERCENT NACL; GRAPHENE OXIDE;
D O I
10.1016/j.molliq.2020.113239
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Locust Bean Gum(LBG) was studied as a novel and eco-friendly corrosion inhibitor using experimental and theoretical calculation methods. These research methods include open-circuit potential (OCP), potentiodynamic polarization curves (PDP), electrochemical impedance spectroscopy (EIS), surface morphology analysis (AFM and SEM), quantum chemical calculations (QCC), and molecular dynamics simulations (MDS). Potentiodynamic polarization test data shows that when the concentration of LBG is 5 mM at 298 K, the corrosion inhibition efficiency of LBG is 89.8% for Q235 steel in 0.5 M H2SO4 solution. AFM and SEM morphology maps convincingly confirm the data of electrochemical tests. The adsorption of LBG on Q235 steel/solution interface was consistent with Langmuir single-layer model. In addition, theoretical calculations show that LBG can show excellent corrosion inhibition performance. (C) 2020 Elsevier B.V. All rights reserved.
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页数:12
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