Excess enthalpies of binary mixtures of 1-hexene with some branched alkanes at the temperature 298.15 K

被引：29

作者：

Wang, ZH ^{[1
]}

Benson, GC ^{[1
]}

Lu, BCY ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem Engn, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2004年 / 36卷 / 01期

关键词：

excess enthalpy; binary mixture; 1-hexene; branched alkanes; Liebermann-Fried model;

D O I：

10.1016/j.jct.2003.09.004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Measurements of excess molar enthalpies at the temperature 298.15 K in a flow microcalorimeter are reported for the five binary mixtures formed by mixing 1-hexene with the branched alkanes: 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane, and 2,2,4-trimethylpentane. Smooth Redlich-Kister representations of the results are described. It was found that the Liebermann-Fried model also provided good representations of the results. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：45 / 47

页数：3

共 10 条

[1] EXCESS-ENTHALPIES OF BINARY-MIXTURES OF NORMAL-HEPTANE WITH HEXANE ISOMERS
KIMURA, F
BENSON, GC
HALPIN, CJ
[J]. FLUID PHASE EQUILIBRIA, 1983, 11 (03) : 245 - 250
[2] KUMARAN MK, 1984, J CHEM ENG DATA, P66
[3] TEMPERATURE DEPENDENCE OF EXCESS GIBBS FREE-ENERGY OF BINARY NONASSOCIATED MIXTURES
LIEBERMANN, E
FRIED, V
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1972, 11 (03): : 354 - +
[4] ESTIMATION OF EXCESS GIBBS FREE-ENERGY AND ENTHALPY OF MIXING OF BINARY NONASSOCIATED MIXTURES
LIEBERMANN, E
FRIED, V
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1972, 11 (03): : 350 - +
[5] Excess enthalpies and (vapour plus liquid) equilibrium for (oxygenated additive plus n-alkane)
Peng, DY
Wang, ZH
Benson, GC
Lu, BCY
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2001, 33 (01) : 83 - 93
[6] RIDDICK JA, 1986, TECHNIQUES CHEM, V2, P119
[7] APPLICATION OF A FLOW MICROCALORIMETER TO DETERMINE EXCESS ENTHALPIES OF BINARY-MIXTURES OF NONELECTROLYTES
TANAKA, R
DARCY, PJ
BENSON, GC
[J]. THERMOCHIMICA ACTA, 1975, 11 (02) : 163 - 175
[8] *THERM RES CTR TEX, TRC THERM TABL HYDR
[9] WANG Z, 2003, UNPUB J CHEM ENG DAT
[10] Excess enthalpies of {ethyl tert-butylether plus hexane plus heptane, or octane} at the temperature 298.15 K
Wang, ZH
Peng, DY
Benson, GC
Lu, BCY
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2001, 33 (09) : 1181 - 1191

← 1 →