B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes

被引：119
|
作者：
Rubin, M [1 ]
Gevorgyan, V [1 ]
机构：
[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 17期
关键词：
D O I：
10.1021/ol016300i
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)(3) has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.
引用
收藏
页码：2705 / 2707
页数：3
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