Synthesis and characterization of ZrO2 nanoparticles for optical and electrochemical applications

被引：37

作者：

Channu, V. S. Reddy ^{[1
]}

Kalluru, Rajamohan R. ^{[2
]}

Schlesinger, Maik ^{[3
]}

Mehring, Michael ^{[3
]}

Holze, Rudolf ^{[1
]}

机构：

[1] Tech Univ Chemnitz, AG Elektrochem, Inst Chem, D-09107 Chemnitz, Germany

[2] Jawaharlal Nehru Technol Univ Hyderabad, KITE Coll Profess Engn Sci, Shabad 509217, India

[3] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2011年 / 386卷 / 1-3期

关键词：

Nanoparticles; Reflux method; Rheological body; Morphology; Cyclic voltammetry; CORE-SHELL NANOPARTICLES; HIGHLY CRYSTALLINE; SOLID-STATE; MONODISPERSE; ZIRCONIA; SIZE; NANOCRYSTALLITES; CHEMISTRY; POWDERS;

D O I：

10.1016/j.colsurfa.2011.07.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cubic phase ZrO2 and mixed phases of monoclinic and cubic ZrO2 nanoparticles were synthesized. The obtained pristine products were characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), optical absorption spectroscopy, photoluminescence (PL) spectroscopy and cyclic voltammetry (CV). The XRD confirms cubic structure of the product prepared by under reflux conditions. The product obtained by rheological body synthesis had a mixed phase structure of cubic and monoclinic type. TEM analysis of the as-synthesized powders shows particles with spherical shape and sizes in the range from 10 to 100 nm. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：151 / 157

页数：7

共 33 条

[1]

[Anonymous], 2001, THESIS U TWENTE ENSC

[2] Size dependence of structural metastability in semiconductor nanocrystals [J].

Chen, CC ;

Herhold, AB ;

Johnson, CS ;

Alivisatos, AP .

SCIENCE, 1997, 276 (5311) :398-401

[3] Ionic conductivity of plasma-sprayed nanocrystalline yttria-stabilized zirconia electrolyte for solid oxide fuel cells [J].

Chen, Y. ;

Omar, S. ;

Keshri, A. K. ;

Balani, K. ;

Babu, K. ;

Nino, J. C. ;

Seal, S. ;

Agarwal, A. .

SCRIPTA MATERIALIA, 2009, 60 (11) :1023-1026

[4]

CHRASKA T, 2000, MAT SCI ENG A-STRUCT, V286, P78

[5] Electrochemistry of vanadium-doped tetragonal and monoclinic ZrO2 attached to graphite/polyester composite electrodes [J].

Doménech, A ;

Alarcón, J .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2002, 6 (07) :443-450

[6] Color-selective semiconductor nanocrystal laser [J].

Eisler, HJ ;

Sundar, VC ;

Bawendi, MG ;

Walsh, M ;

Smith, HI ;

Klimov, V .

APPLIED PHYSICS LETTERS, 2002, 80 (24) :4614-4616

[7]

Gell M., 1995, MAT SCI ENG A-STRUCT, V204, P51

[8]

Gleiter H., 1992, Nanostructured Materials, V1, P1, DOI 10.1016/0965-9773(92)90045-Y

[9] LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].

HAGFELDT, A ;

GRATZEL, M .

CHEMICAL REVIEWS, 1995, 95 (01) :49-68

[10]

HASSEL BAV, 1992, SOLID STATE IONICS, V51, P175

← 1 2 3 4 →