Stereoselective hydrothiolation of alkynes catalyzed by cesium base: Facile access to (Z)-1-alkenyl sulfides

被引：143

作者：

Kondoh, A ^{[1
]}

Takami, K ^{[1
]}

Yorimitsu, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 16期

关键词：

D O I：

10.1021/jo050931z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alkyne with alkanethiol in the presence of a catalytic amount of cesium carbonate and a radical inhibitor in DMSO provides the corresponding adduct, (Z)-1-alkenyl alkyl sulfide, in good yield with high selectivity.

引用

页码：6468 / 6473

页数：6

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