Bis(μ-carboxylatoethylphosphonato)bis-[aqua(2,2′-bipyridine)manganese(II)]

被引：4
|
作者：
Ying, Shao-Ming [1 ]
Chen, Yun [2 ]
Luo, Qiu-Yan [1 ]
Xv, Ya-Ping [1 ]
Liu, Dong-Sheng [1 ]
机构：
[1] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China
[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536807065142
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Mn-2(HO3PCH2CH2COO)(2)(C8H8N2)(2)( H2O)(2)], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O-H center dot center dot center dot O hydrogen bonds and pi-pi stacking interactions [centroid-centroid distance 4.2754 (4) angstrom].
引用
收藏
页码：M166 / U1572
页数：10
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