Toward the Synthesis of Muironolide A: Synthesis and Structure of Heteroleptic Lanthanide-Terpyridine Complexes with 2-Oxo Amides

被引：5
作者：
Young, Kyle [1 ]
Xiao, Qing [1 ]
Zakarian, Armen [1 ]
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 11期
基金：
美国国家科学基金会;
关键词：
Lanthanides; Natural products; Muironolide A; Intramolecular Diels-Alder reaction; Cycloaddition; ORGANIC-SYNTHESIS; ISOINDOLINONE CORE; MICHAEL ADDITION; CHEMISTRY;
D O I：
10.1002/ejoc.201500174
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A lanthanide-catalyzed intramolecular Diels-Alder (IMDA) reaction en route to the synthesis of muironolide A is described, along with detailed crystallographic structural studies of lanthanide complexes between -oxo amides and terpyridine. The X-ray crystallographic studies are first examples of nonsymmetric heteroleptic complexes of lanthanides with -oxo carbonyl compounds, which reveal several structural properties that could be exploited in the development of catalytic reactions with lanthanides.
引用
收藏
页码：2337 / 2341
页数：5
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