Synthesis and crystal structure of coordination compound of cobalt(II) pyridine-2,6-dicarboxylate with 1,10-phenanthroline

被引：0
|
作者：
Yin, XJ [1 ]
Jiang, YM [1 ]
机构：
[1] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2001年 / 20卷 / 04期
关键词：
cobalt; pydinine-2,6-dicarboxylate; 1,10-phenanthroline; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cobalt pyridine-2,6-dicarboxylate ternary complex [Co(DPC)(phen)(H2O)]. 2H(2)O (C19H17CoN3O7, M-r=458.29) has been synthesized in the solution of cobaltous(II) chloride salt, where DPC=pyridine-2,6-dicarboxylate and phen=1,10-phenanthroline. The molecular and crystal structure was determined by single-crystal X-ray diffraction,the results indicate that the complex crystal is triclinic with space group P1 and unit cell parameters: a = 7.818(1), b=9.290(2), c=14.048(3)Angstrom; alpha =81.477(1),beta =81.456(8), gamma =72.970(2)degrees, V= 958.7(3)Angstrom (3), Z=2, F(000)= 470, D-c =1.588Mg/m, mu (MoK alpha)--0.944mm(-1). In the structure the Co(II) ion is six-coordinated to form a distorted octahedron.
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页码：299 / 301
页数：3
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