Curing Kinetics of DGEBA Epoxy Resin Modified by Poly (phthalazinone ether ketone) (PPEK)

被引：9
|
作者：
Xu, Yajuan [2 ]
Zhou, Sikai [2 ]
Liao, Gongxiong [1 ]
Jian, Xigao [1 ,3 ]
机构：
[1] Dalian Univ Technol, Dept Polymer Sci & Mat, Dalian 116012, Peoples R China
[2] Luoyang Inst Sci & Technol, Sch Mat Sci & Engn, Luoyang, Peoples R China
[3] Liaoning Prov High Performance Resins Engn Res Ct, Dalian, Peoples R China
来源：
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2012年 / 51卷 / 02期
基金：
美国国家科学基金会;
关键词：
Blending; Curing kinetics; Epoxy resins; poly (phthalazinone ether ketone) (PPEK); CURE KINETICS; POLY(ETHER IMIDE); MECHANICAL-PROPERTIES; DIGLYCIDYL ETHER; BLENDS; BEHAVIOR; AMINE; MISCIBILITY; MORPHOLOGY; SYSTEM;
D O I：
10.1080/03602559.2011.578294
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The cure kinetics of diaminodiphenylsulfone-cured diglycidyl ether of bisphenol A epoxy resin (DGEBA) and its blends with poly (phthalazinone ether ketone) (PPEK) were investigated by isothermal differential scanning calorimetry (DSC). The results were applied to the Arrhenius equation and the phenomenological model of Kamal. The Arrhenius activation energy increased with increasing PPEK content. The experimental reactions rates agreed well with that of the theoretical in the initial stages of the reaction, but diffusion control was incorporated to describe the cure in the latter stages. The cure mechanism remained broadly autocatalytic in nature regardless of PPEK concentration and the cure temperature.
引用
收藏
页码：128 / 133
页数：6
相关论文
共 50 条
  • [11] Mechanism and Kinetics of Curing of Diglycidyl Ether of Bisphenol A (DGEBA) Resin by Chitosan
    Balasubramani, Praveen Kumar
    Iroh, Jude O.
    POLYMER ENGINEERING AND SCIENCE, 2017, 57 (08): : 865 - 874
  • [12] Cure Kinetics, Phase Behaviors, and Fracture Properties of Bismaleimide Resin Toughened by Poly(phthalazinone ether ketone)
    Han, Yongjin
    Liao, Gongxiong
    Xu, Yajuan
    Yu, Guipeng
    Jian, Xigao
    POLYMER ENGINEERING AND SCIENCE, 2009, 49 (12): : 2301 - 2308
  • [13] THE CURING REACTION OF POLY(ETHER-SULFONE)-MODIFIED EPOXY-RESIN
    CHEN, YS
    LEE, JS
    YU, TL
    CHEN, JC
    CHEN, WY
    CHENG, MC
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1995, 196 (11) : 3447 - 3458
  • [14] Optimization and characterization of poly(phthalazinone ether ketone) (PPEK) heat-resistant porous fiberous mat by electrospinning
    Shi, R.
    Bin, Y. Z.
    Yang, W. X.
    Wang, D.
    Wang, J. Y.
    Jian, X. G.
    APPLIED SURFACE SCIENCE, 2016, 379 : 282 - 290
  • [15] Study of curing kinetics of siloxane-modified DGEBA epoxy resins
    Lin, ST
    Huang, SK
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 62 (10) : 1641 - 1649
  • [16] Curing kinetics of bio-based epoxy resin-toughened DGEBA epoxy resin blendSynthesis and characterization
    Sudheer Kumar
    Sushanta K. Samal
    Smita Mohanty
    Sanjay K. Nayak
    Journal of Thermal Analysis and Calorimetry, 2019, 137 : 1567 - 1578
  • [17] Synthesis and properties of novel poly (phthalazinone ether ketone ketone)
    Liu, YJ
    Jian, XG
    Liu, SJ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (04) : 823 - 826
  • [18] Toughening of Epoxy Resin by Poly(ether ether ketone) with Pendant Fluorocarbon Groups
    Luo, Ye
    Zhang, Ming
    Dang, Guodong
    Li, Yan
    An, Xuefeng
    Chen, Chunhai
    Yi, Xiaosu
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (03) : 1758 - 1765
  • [19] BLENDS OF PHENOLPHTHALEIN POLY(ETHER ETHER KETONE) WITH PHENOXY AND EPOXY-RESIN
    GUO, QP
    HUANG, JY
    LI, BY
    CHEN, TL
    ZHANG, HF
    FENG, ZL
    POLYMER, 1991, 32 (01) : 58 - 65
  • [20] Modified poly(phthalazinone ether ketone) membranes for direct methanol fuel cell
    Zhang, Hongwei
    Zhou, Zhentao
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (05) : 425 - 431
12345