The Application of Nanoemulsions with Different Orange Oil Concentrations to Remediate Crude Oil-Contaminated Soil

The petroleum industry stands out for causing significant environmental risks from contamination of the air, water and soil. The removal of organic pollutants from the environment poses a great technological challenge, making it increasingly necessary to develop efficient clean-up technologies. Surfactant solutions have been used to remediate soils and aquifers contaminated by hydrocarbons or crude oil derivatives. The aim of this study was to develop nanoemulsions and analyze their efficiency in extracting crude oil from a sand sample. The nanoemulsions were prepared by the phase inversion temperature (PIT) method. The oil phase consisted of orange oil and the nonionic surfactant ethoxylated lauryl ether (Ultrol(R) L70) was used to stabilize the nanoemulsions. The surfactant concentrations were varied from 10 to 12 wt% and the oil phase from 5 to 20 wt%. The efficiency of extraction of oil from sand was assessed using the two nanoemulsions that presented the greatest stability (containing 5 wt% oil phase with 12 wt% surfactant and 20 wt% oil phase with 10 wt% surfactant). A 2(3) factorial experimental design with center point was used to evaluate and improve the soil washing process, varying the time, temperature and agitation speed of the system. The highest efficiencies were obtained at 45 degrees C.