Dithiafulvenyl-equipped Ru(II) bis-terpyridine complexes ? Synthesis, photophysical and electrochemical properties

被引：3
|
作者：
Winter, Andreas [1 ,2 ]
Sittig, Maria [1 ,3 ,4 ,5 ,6 ]
Schubert, Ulrich S. [1 ,2 ,3 ]
机构：
[1] Friedrich Schiller Univ Jena, Lab Organ & Macromol Chem IOMC, Humboldtstr 10, D-07743 Jena, Germany
[2] Ctr Energy & Environm Chem Jena CEEC Jena, Philosophenweg 7a, D-07743 Jena, Germany
[3] Friedrich Schiller Univ Jena, Jena Ctr Soft Matter JCSM, Philosophenweg 7, D-07743 Jena, Germany
[4] Friedrich Schiller Univ Jena, Inst Phys Chem IPC, Helmholtzweg 4, D-07743 Jena, Germany
[5] Friedrich Schiller Univ Jena, Abbe Ctr Photon, Helmholtzweg 4, D-07743 Jena, Germany
[6] Leibniz Inst Photon Technol IPhT Jena, Albert Einstein Str 9, D-07745 Jena, Germany
来源：
INORGANICA CHIMICA ACTA | 2020年 / 510卷
关键词：
WALLED CARBON NANOTUBES; BUILDING-BLOCKS; SUPRAMOLECULAR CHEMISTRY; MOLECULAR TWEEZERS; TETRATHIAFULVALENE; TTFV; DONORS; RUTHENIUM(II); SENSITIZERS; DERIVATIVES;
D O I：
10.1016/j.ica.2020.119747
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dithiafulvalenes (DTFs) represent an important class of organic dyes known for their redox-activity and ability to oxidatively dimerize into tetrathiafulvalene vinylogues (TTFVs). These systems, in turn, exhibit a reversible redox-driven conformational switching between a charge neutral cisoid and a dicationic transoid form. Both types of dyes have already been utilized, as organic sensitizers, in dye-sensitized solar cells (DSSCs). A series of DTF- and TTFV-bearing Ru(II) bis-terpyridyl complexes has been prepared and characterized with respect to their photophysical and electrochemical properties. A fundamental study of the model complexes is presented and is of importance for a later incorporation of such chromophores, as sensitizers, into DSSCs. © 2020 Elsevier B.V.
引用
收藏
页数：9
相关论文
共 50 条
  • [31] SYNTHESIS AND THEORETICAL DFT STUDY OF RU(II) COMPLEXES WITH FERROCENYLIC LIGANDS FOR ELECTROCHEMICAL APPLICATIONS
    Parada, Giovanny A.
    Fernandez, Daniel
    Reyes, Andres
    Suarez, Marco F.
    Fadini, Luca
    REVISTA COLOMBIANA DE QUIMICA, 2007, 36 (02): : 199 - 211
  • [32] Syntheses, structures, spectroscopic, electrochemical properties and DFT calculation of Ru(II)-thioarylazoimidazole complexes
    Mondal, T. K.
    Wu, J. -S.
    Lu, T. -H.
    Jasimuddin, Sk.
    Sinha, C.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (21) : 3518 - 3525
  • [33] Mono- and dinuclear Ru(II) complexes of 1,4-bis(3-(2-pyridyl)pyrazol-1-ylmethyl)benzene): Synthesis, structure, photophysical properties and electrochemiluminescent determination of diuretic furosemide
    Wei, Qiao-Hua
    Lei, Yan-Fang
    Duan, Ya-Nan
    Xiao, Fan-Nan
    Li, Mei-Jin
    Chen, Guo-Nan
    DALTON TRANSACTIONS, 2011, 40 (43) : 11636 - 11642
  • [34] Bucky ligands: Synthesis, ruthenium(II) complexes, and electrochemical properties
    Armspach, D
    Constable, EC
    Diederich, F
    Housecroft, CE
    Nierengarten, JF
    CHEMISTRY-A EUROPEAN JOURNAL, 1998, 4 (04) : 723 - 733
  • [35] Star-shaped triphenylamine terminated difluoroboron β-diketonate complexes: synthesis, photophysical and electrochemical properties
    Qian, Chong
    Hong, Guanghui
    Liu, Mingyang
    Xue, Pengchong
    Lu, Ran
    TETRAHEDRON, 2014, 70 (25) : 3935 - 3942
  • [36] Synthesis, characterization and investigation of photophysical and biological properties of Cu(II) and Zn(II) complexes of benzimidazole ligands
    Sherwani, Ibrahim Ali Hamad Ameen
    Kose, Aysegul
    Gungor, Ozge
    Kirpik, Hilal
    Gungor, Seyit Ali
    Kose, Muhammet
    APPLIED ORGANOMETALLIC CHEMISTRY, 2022, 36 (04)
  • [37] New -extended catecholato complexes of Pt(ii) and Pd(ii) containing a benzothienobenzothiophene (BTBT) moiety: synthesis, electrochemical behavior and charge transfer properties
    Tahara, Keishiro
    Ashihara, Yuya
    Higashino, Toshiki
    Ozawa, Yoshiki
    Kadoya, Tomofumi
    Sugimoto, Kunihisa
    Ueda, Akira
    Mori, Hatsumi
    Abe, Masaaki
    DALTON TRANSACTIONS, 2019, 48 (21) : 7367 - 7377
  • [38] Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes
    ADEWALE O ADELOYE
    PETER A AJIBADE
    FRANCES R CUMMINGS
    LUKAS J LE ROUX
    SAMPSON N MAMPHWELI
    EDSON L MEYER
    Journal of Chemical Sciences, 2013, 125 : 17 - 27
  • [39] Synthesis, characterization, photophysical, and redox properties of three trinuclear Ru(II) polypyridyl complexes possessing 5-amino-1,10-phenanthroline ligands
    He, Chixian
    Yu, Shiwen
    Ma, Shuye
    Cheng, Feixiang
    TRANSITION METAL CHEMISTRY, 2019, 44 (06) : 515 - 524
  • [40] Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes
    Adeloye, Adewale O.
    Ajibade, Peter A.
    Cummings, Frances R.
    Le Roux, Lukas J.
    Mamphweli, Sampson N.
    Meyer, Edson L.
    JOURNAL OF CHEMICAL SCIENCES, 2013, 125 (01) : 17 - 27
12345