Structuring of bridged silsesquioxanes via cooperative weak interactions: H-bonding of urea groups and hydrophobic interactions of long alkylene chains

被引:45
|
作者
Moreau, JJE [1 ]
Pichon, BP [1 ]
Bied, C [1 ]
Man, MWC [1 ]
机构
[1] Ecole Natl Super Chim Montpellier, Lab Heterochim Mol & Macromol, UMR 5076, CNRS, F-34296 Montpellier, France
关键词
D O I
10.1039/b504635a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lamellar-bridged silsesquioxanes were obtained by the acid-catalysed hydrolytic condensation of a series of bissilylated organobridged molecular precursors. It was found that exploiting cooperative effects between the molecular interactions created by long hydrophobic hydrocarbon chains and the H-bonding between urea groups in the precursors favoured the nanostructuring of the corresponding hybrid silicas.
引用
收藏
页码:3929 / 3936
页数:8
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