Properties of mineral filled poly(lactic acid)/poly(methyl methacrylate) blend

被引：2

作者：

Gonzalez-Garzon, Mauricio ^{[1
]}

Shahbikian, Shant ^{[1
]}

Huneault, Michel A. ^{[1
]}

机构：

[1] Univ Sherbrooke, Dept Chem & Biotechnol Engn, 2500 Blvd Univ, Sherbrooke, PQ J1K 2R1, Canada

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2019年 / 136卷 / 10期

关键词：

blends; minerals; poly(lactic acid); poly(methyl methacrylate); reinforcement; LOW-MOLECULAR-WEIGHT; POLYLACTIDE/MONTMORILLONITE NANOCOMPOSITES; HYDROLYTIC DEGRADATION; MECHANICAL-PROPERTIES; THERMAL-STABILITY; PLA COMPOSITES; POLY(L-LACTIDE); POLYLACTIDE; MORPHOLOGY; ACID);

D O I：

10.1002/app.46927

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This study examines the influence of three different minerals, that is, clay, calcium carbonate, and quartz on the physical, thermal, and mechanical properties of poly(lactic acid) (PLA)/poly(methyl methacrylate) blend. Rheological behavior and phase structure were initially studied by small-amplitude oscillatory shear rheology. Clay- and quartz-filled materials presented an increase in viscosity at low frequency associated with the presence of a yield stress. However, this behavior was not observed for calcium carbonate filled materials due to a matrix degradation effect. To elucidate this aspect, thermal stability and thermal properties were examined by thermogravimetric analysis and differential scanning calorimetry, showing that calcium carbonate promotes degradation of the PLA phase. No nucleating effect was observed in the presence of the minerals. Dynamical mechanical analysis and mechanical characterization revealed an increase of the overall softening temperature and, a reinforcing effect for clay- and quartz-based composites. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 46927.

引用

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