Synthesis, Crystal Structure and Catalytic Activity of a Bimetallic Rhodium Complex with 1,5-Cyclooctadiene and 2,2′-Bipyridine

被引：0
作者：
Hu Jiu-Rong [1 ]
Yan Wei-Hong [2 ]
Luo Nian-Hua [1 ]
Dung Rou-Jie [1 ]
Huang Rong-Li [1 ]
Ye Hong-De [1 ]
机构：
[1] Shangrao Normal Univ, Higher Inst Jiangxi Prov, Key Lab Appl Organ Chem, Sch Chem & Chem Engn, Shangrao 334001, Jiangxi, Peoples R China
[2] Nanyang Inst Technol, Sch Biol & Chem Engn, Nanyang 473004, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Rh(1) complex; 2,2 '-bipyridine; crystal structure; hydroformylation; MOLECULAR-STRUCTURES; IRIDIUM COMPLEXES; LIGANDS;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new complex [Rh(COD)(2,2'-bipy)]center dot[Rh(COD)Cl-2] (COD = 1,5-cyclooctadiene, 2,2'-bipy = 2,2'-bipyridine) has been synthesized and characterized by elemental analyses, NMR and single-crystal X-ray diffraction. The complex crystallizes in triclinic system, space group P (1) over bar with a = 7.4782(14), b = 10.1400(11), c = 16.6982(14) angstrom, a = 103.494(11), beta = 91.996(13), gamma = 103.829(12)degrees, C26H32Cl2N2Rh2, M-r = 649.26, V = 1190.0(3) angstrom(3), D-c = 1.812 g/cm(3), Z= 2, F(000) = 652, mu(MoK alpha) = 1.629 mm(-1), R = 0.0286 and wR = 0.0463 for 3718 observed reflections (I > 2 sigma(I)). The complex was linked to form 1D chains by hydrogen bonding interaction (C-H center dot center dot center dot Cl), and further to construct a 2D layer structure by pi center dot center dot center dot pi stacking interactions between the pyridine rings of 2,2'-bipy ligands. The hydroformylation catalyzed by the title complex was also studied.
引用
收藏
页码：1107 / 1112
页数：6
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