A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

被引：59

作者：

He, Hongming ^{[1
]}

Song, Yang ^{[1
]}

Zhang, Chuanqi ^{[1
]}

Sun, Fuxing ^{[1
]}

Yuan, Rongrong ^{[1
]}

Bian, Zheng ^{[2
]}

Gao, Lianxun ^{[2
]}

Zhu, Guangshan ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 46期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; CO2/CH4; SELECTIVITY; LIGHT-HYDROCARBONS; BUILDING-BLOCKS; SINGLE-CRYSTAL; SORPTION; CO2/N-2; GAS; SEPARATION; TOPOLOGY;

D O I：

10.1039/c5cc01281c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.

引用

页码：9463 / 9466

页数：4

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