Mononuclear chelating diselenito complexes of platinum(II) and the crystal structure of bis-triphenylphosphine(diselenito-O, O′) platinum(II) -: Preference for hard versus soft ligands of the cis-Pt(PPh3)2 moiety?

被引：6

作者：

Battan, L

Manassero, M

Pasini, A

机构：

[1] Univ Milan, Ctr CNR, Dipartimento Chim Inorgan Metallorgan & Anali, I-20133 Milan, Italy

[2] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 11期

关键词：

chelating diselenito; methylsulfanylacetato; methylsulfanylbenzoato; platinum phosphine complexes;

D O I：

10.1016/S1387-7003(01)00283-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An OO' chelating diselenito is found in the X-ray structure of [Pt(PPh3)(2)(Se2O5)]. The possible preference of the cis-Pt(PPh3)(2) moiety towards O, rather than softer donor ligand atoms, is briefly discussed on the basis of other examples. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：606 / 609

页数：4

共 19 条

[1]

BATTAN L, IN PRESS

[2] CRYSTAL-STRUCTURE OF MONOCLINIC MNSE2O5 AND COMPARATIVE MAGNETIC STUDY OF MONOCLINIC AND ORTHORHOMBIC VARIETIES [J].