p-Cu2O-shell/n-TiO2-nanowire-core heterostucture photodiodes

被引:40
作者
Tsai, Tsung-Ying [2 ,3 ]
Chang, Shoou-Jinn [2 ,3 ]
Hsueh, Ting-Jen [1 ]
Hsueh, Han-Ting [1 ]
Weng, Wen-Yin [2 ,3 ]
Hsu, Cheng-Liang [4 ]
Dai, Bau-Tong [1 ]
机构
[1] Natl Nano Device Labs, Tainan 741, Taiwan
[2] Natl Cheng Kung Univ, Inst Microelect, Tainan 701, Taiwan
[3] Natl Cheng Kung Univ, Dept Elect Engn, Ctr Micro Nano Sci & Technol, Adv Optoelect Technol Ctr, Tainan 701, Taiwan
[4] Natl Univ Tainan, Dept Elect Engn, Tainan 700, Taiwan
来源
NANOSCALE RESEARCH LETTERS | 2011年 / 6卷
关键词
FILM; TIO2; CU2O;
D O I
10.1186/1556-276X-6-575
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study reports the deposition of cuprous oxide [Cu2O] onto titanium dioxide [TiO2] nanowires [NWs] prepared on TiO2/glass templates. The average length and average diameter of these thermally oxidized and evaporated TiO2 NWs are 0.1 to 0.4 mu m and 30 to 100 nm, respectively. The deposited Cu2O fills gaps between the TiO2 NWs with good step coverage to form nanoshells surrounding the TiO2 cores. The p-Cu2O/n-TiO2 NW heterostructure exhibits a rectifying behavior with a sharp turn-on at approximately 0.9 V. Furthermore, the fabricated p-Cu2O-shell/n-TiO2-nanowire-core photodiodes exhibit reasonably large photocurrent-to-dark-current contrast ratios and fast responses.
引用
收藏
页码:1 / 7
页数:7
相关论文
共 27 条
[1]   A sol-gel approach to nanophasic copper oxide thin films [J].
Armelao, L ;
Barreca, D ;
Bertapelle, M ;
Bottaro, G ;
Sada, C ;
Tondello, E .
THIN SOLID FILMS, 2003, 442 (1-2) :48-52
[2]   GaN-based p-i-n sensors with ITO contacts [J].
Chang, SJ ;
Ko, TK ;
Su, YK ;
Chiou, YZ ;
Chang, CS ;
Shei, SC ;
Sheu, JK ;
Lai, WC ;
Lin, YC ;
Chen, WS ;
Shen, CF .
IEEE SENSORS JOURNAL, 2006, 6 (02) :406-411
[3]   Conversion efficiency of 10.8% by a dye-sensitized solar cell using a TiO2 electrode with high haze [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
APPLIED PHYSICS LETTERS, 2006, 88 (22)
[4]   Investigation of photoelectrochemical characteristics of n-type Cu2O films [J].
Fernando, CAN ;
Wetthasinghe, SK .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 63 (03) :299-308
[5]   PHOTO-VOLTAIC EFFECTS IN CU2O-CU SOLAR-CELLS GROWN BY ANODIC-OXIDATION [J].
FORTIN, E ;
MASSON, D .
SOLID-STATE ELECTRONICS, 1982, 25 (04) :281-283
[6]   ELECTRONIC-STRUCTURE OF CU2O AND CUO [J].
GHIJSEN, J ;
TJENG, LH ;
VANELP, J ;
ESKES, H ;
WESTERINK, J ;
SAWATZKY, GA ;
CZYZYK, MT .
PHYSICAL REVIEW B, 1988, 38 (16) :11322-11330
[7]   Electrochemical deposition of copper(I) oxide films [J].
Golden, TD ;
Shumsky, MG ;
Zhou, YC ;
VanderWerf, RA ;
VanLeeuwen, RA ;
Switzer, JA .
CHEMISTRY OF MATERIALS, 1996, 8 (10) :2499-2504
[8]   INVESTIGATION OF METAL-OXIDE CUPROUS-OXIDE HETEROJUNCTION SOLAR-CELLS [J].
HERION, J ;
NIEKISCH, EA ;
SCHARL, G .
SOLAR ENERGY MATERIALS, 1980, 4 (01) :101-112
[9]   Si Nanowire-Based Photovoltaic Devices Prepared at Various Temperatures [J].
Hsueh, Ting-Jen ;
Chen, Hsin-Yuan ;
Tsai, Tsung-Ying ;
Weng, Wen-Yin ;
Yeh, Yu-Ming ;
Dai, Bau-Tong ;
Shieh, Jia-Min .
IEEE ELECTRON DEVICE LETTERS, 2010, 31 (11) :1275-1277
[10]   Passivation of defects in polycrystalline Cu2O thin films by hydrogen or cyanide treatment [J].
Ishizuka, S ;
Kato, S ;
Okamoto, Y ;
Sakurai, T ;
Akimoto, K ;
Fujiwara, N ;
Kobayashi, H .
APPLIED SURFACE SCIENCE, 2003, 216 (1-4) :94-97