Chromium(III) Potentiometric Sensor Based on Para-Tertiary-Butyl Calix[4]arene

被引：3
|
作者：
Sadeghi, Hayedeh Bagheri [1 ]
Tamaddon, Atefeh [1 ]
Afifinia, Hadi [1 ]
Almasian, Nasim [1 ]
Bozorgvar, Fatemeh [1 ]
Mollaei, Somayeh [1 ]
机构：
[1] Islamic Azad Univ, Dept Chem, Tehran Cent Branch, Tehran, Iran
来源：
ELECTROANALYSIS | 2011年 / 23卷 / 10期
关键词：
p-tert-butyl calix[4]arene; Chromium(III); Ion selective electrodes; ION-SELECTIVE ELECTRODES; WATER; PRECONCENTRATION; SPECIATION; CR(III); CR(VI);
D O I：
10.1002/elan.201100220
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A new chromium(III) PVC membrane sensor incorporating p-tertiary-butyl calix[4]arene as ionophore, potassium tetrakis as additive and dibutyl phthalate (DBP) as plasticizer was constructed. The electrode exhibited an excellent potentiometric response over a wide concentration range of 1.0x10(-7)-1.0x10(-1) M with a Nernstian slope of 20 +/- 0.5 mV per decade. The detection limit was 5.0x10(-8) M. The electrode showed a better performance over a pH range of 3.0-8.0, and had a short response time of about <15 s. The electrode was successfully applied to potentiometric titration of Cr (III) with EDTA and for direct determination of chromium(III) in waste water.
引用
收藏
页码：2472 / 2478
页数：7
相关论文
共 50 条
  • [31] Toxicity and biodistribution of para-sulfonato-calix[4] arene in mice
    Coleman, Anthony W.
    Jebors, Said
    Cecillon, Sebastien
    Perret, Pascale
    Garin, Dominique
    Marti-Battle, Daniele
    Moulin, Marcelle
    NEW JOURNAL OF CHEMISTRY, 2008, 32 (05) : 780 - 782
  • [32] Proton conductivity of calix[4]arene-para-sulfonic acids
    Shmygleva, L. V.
    Pisareva, A. V.
    Pisarev, R. V.
    Ukshe, A. E.
    Dobrovol'skii, Yu A.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2013, 49 (08) : 801 - 806
  • [33] A molecular turnstile in para-octanoyl calix[4]arene nanocapsules
    Ananchenko, Gennady S.
    Udachin, Konstantin A.
    Pojarova, Michaela
    Jebors, Said
    Coleman, Anthony W.
    Ripmeester, John A.
    CHEMICAL COMMUNICATIONS, 2007, (07) : 707 - 709
  • [34] Vibrational spectra, co-operative intramolecular hydrogen bonding and conformations of calix[4]arene and thiacalix[4]arene molecules and their para-tert-butyl derivatives
    Katsyuba, S
    Kovalenko, V
    Chernova, A
    Vandyukova, E
    Zverev, V
    Shagidullin, R
    Antipin, I
    Solovieva, S
    Stoikov, I
    Konovalov, A
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (14) : 2558 - 2565
  • [35] Proton conductivity of calix[4]arene-para-sulfonic acids
    L. V. Shmygleva
    A. V. Pisareva
    R. V. Pisarev
    A. E. Ukshe
    Yu. A. Dobrovol’skii
    Russian Journal of Electrochemistry, 2013, 49 : 801 - 806
  • [36] Potentiometric detection of chromium (III) on the carbon fiber electrode modified by n-hexyl calix[4]resorcinarene
    Qiao, Qiuju
    Jin, Gendi
    Hu, Xiaoya
    SENSORS AND ACTUATORS B-CHEMICAL, 2011, 160 (01): : 87 - 93
  • [37] Monitoring of the prohibited 2-phenethylamine in dietary supplements using a t-Butyl calix[8]arene/Ag/CuO composite-based potentiometric sensor
    Abdelaal, Sarah H.
    El Azab, Noha F.
    Hassan, Said A.
    El-Kosasy, Amira M.
    MICROCHEMICAL JOURNAL, 2024, 201
  • [38] A novel colorimetric and fluorescent sensor based on calix[4]arene possessing triphenylamine units
    Erdemir, Serkan
    Malkondu, Sait
    Kocyigit, Ozcan
    Alici, Onder
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 114 : 190 - 196
  • [39] Chromium(III)-selective electrode using p-(4-Acetanilidazo)calix[4]arene as an ionophore in PVC Matrix
    Kumar, Pankaj
    Shim, Yoon-Bo
    Bulletin of the Korean Chemical Society, 2008, 29 (12) : 2471 - 2476
  • [40] Calix[4]arene-based Cs plus selective optical sensor.
    Ji, HF
    Brown, GM
    Dabestani, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U1066 - U1066
12345