N-Halosuccinimides as Precatalysts for C-, N-, O-, and X-Nucleophilic Substitution Reactions of Alcohols under Mild Reaction Conditions

被引:8
|
作者
Ajvazi, Njomza [1 ]
Stavber, Stojan [1 ,2 ]
机构
[1] Jozef Stefan Int Postgrad Sch, Jamova 39, Ljubljana 1000, Slovenia
[2] Jozef Stefan Inst, Jamova 39, Ljubljana 1000, Slovenia
关键词
alcohols; N-halosuccinimides; C-C or C-heteroatom bond formation; solvent-free; green chemistry; EFFECTIVE CATALYST; CARBONYL-COMPOUNDS; BENZYLIC ALCOHOLS; BROMOSUCCINIMIDE; ALKYLATION; STRATEGY; NBS;
D O I
10.3390/catal10040460
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N-halosuccinimides (chloro, bromo, and iodo, respectively) were introduced, tested, and applied as efficient and non-metal precatalysts for C-, N-, O-, and X-nucleophilic substitution reactions of alcohols under solvent-free reaction conditions (SFRC) or under high substrate concentration reaction conditions (HCRC) efficiently and selectively, into the corresponding products.
引用
收藏
页数:12
相关论文
共 23 条
  • [1] Niobium(V) pentachloride: an efficient catalyst for C-, N-, O-, and S-nucleophilic substitution reactions of benzylic alcohols
    Yadav, J. S.
    Bhunia, Dinesh C.
    Krishna, K. Vamshi
    Srihari, P.
    TETRAHEDRON LETTERS, 2007, 48 (47) : 8306 - 8310
  • [2] α-Halo Ketones in C-, N-, O-, and S-Alkylation Reactions
    I. K. Moiseev
    N. V. Makarova
    M. N. Zemtsova
    Russian Journal of Organic Chemistry, 2003, 39 : 1685 - 1701
  • [3] N-Iodosuccinimide as a Precatalyst for C-N Bond-Forming Reactions from Alcohols under Mild Reaction Conditions
    Ajvazi, Njomza
    Stavber, Stojan
    CATALYSTS, 2022, 12 (11)
  • [4] BiCl3-catalyzed propargylic substitution reaction of propargylic alcohols with C-, O-, S- and N-centered nucleophiles
    Zhan, Zhuang-ping
    Yang, Wen-zhen
    Yang, Rui-feng
    Yu, Jing-liang
    Li, Jun-ping
    Liu, Hui-juan
    CHEMICAL COMMUNICATIONS, 2006, (31) : 3352 - 3354
  • [5] POLY 121-Unsaturated polyimide prepared under mild reaction conditions by nucleophilic substitution reaction through C-N bond formation
    Parthiban, Anbanandam
    Yu, Han
    Chai, Christina L. L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
  • [6] Bromophilic substitution/carbophilic substitution cascade reactions of α,α-dibromo-2-methoxyacetophenone with C-, N- and O-nucleophiles
    Tatar, Jovana
    Markovic, Rade
    Stojanovic, Milovan
    Baranac-Stojanovic, Marija
    TETRAHEDRON LETTERS, 2010, 51 (37) : 4851 - 4855
  • [7] PMA-SiO2:: A heterogenous catalyst for O-, S-, and N-nucleophilic substitution reactions of aryl propargyl alcohols
    Srihari, P.
    Reddy, J. Shyam Sunder
    Bhunia, Dinesh C.
    Mandal, S. S.
    Yadav, J. S.
    SYNTHETIC COMMUNICATIONS, 2008, 38 (09) : 1448 - 1455
  • [8] Heterobimetallic Pd-Sn Catalysis: Michael Addition Reaction with C-, N-, O-, and S-Nucleophiles and in Situ Diagnostics
    Das, Debjit
    Pratihar, Sanjay
    Roy, Sujit
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (06): : 2430 - 2442
  • [9] The umpolung of substituent effect in nucleophilic aromatic substitution. A new approach to the synthesis of N,N-disubstituted melamines (triazine triskelions) under mild reaction conditions
    Kolesinska, Beata
    Kaminski, Zbigniew J.
    TETRAHEDRON, 2009, 65 (18) : 3573 - 3576
  • [10] Nucleophilic substitution in the series of (1,2,3-triazol-1-yl)-1,2,5-oxadiazoles. Reactions with N-, O-, and S-nucleophiles
    V. Yu. Rozhkov
    L. V. Batog
    M. I. Struchkova
    Russian Chemical Bulletin, 2005, 54 : 1923 - 1934