Catalytic dihydroxylation of olefins with hydrogen peroxide: An organic-solvent- and metal-free system

被引：160
作者：
Usui, Y [1 ]
Sato, K [1 ]
Tanaka, M [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, AIST, Res Inst Green Technol, Tsukuba, Ibaraki 3058565, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 45期
关键词：
alkenes; dihydroxylation; green chemistry; hydrogen peroxide; oxidation;
D O I：
10.1002/anie.200352568
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Green and convenient: Olefins are oxidized to 1,2-diols in high yield with 30% H2O2 in the presence of resin-supported sulfonic acid (see scheme) under metal-free conditions without any organic solvent. The catalyst can be recycled easily and is effective for at least 10 cycles.
引用
收藏
页码：5623 / 5625
页数：3
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