Catalytic dihydroxylation of olefins with hydrogen peroxide: An organic-solvent- and metal-free system

被引：162

作者：

Usui, Y ^{[1
]}

Sato, K ^{[1
]}

Tanaka, M ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, AIST, Res Inst Green Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 45期

关键词：

alkenes; dihydroxylation; green chemistry; hydrogen peroxide; oxidation;

D O I：

10.1002/anie.200352568

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Green and convenient: Olefins are oxidized to 1,2-diols in high yield with 30% H2O2 in the presence of resin-supported sulfonic acid (see scheme) under metal-free conditions without any organic solvent. The catalyst can be recycled easily and is effective for at least 10 cycles.

引用

页码：5623 / 5625

页数：3

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