Hydrogen Storage Properties of the Mg(NH3)6Cl2-LiH Combined System

Metal ammine complexes (MACs) were recently regarded as one of promising materials for reversible hydrogen storage due to their high hydrogen content. In this work, a first attempt is conducted to elucidate the hydrogen storage reversibility by combining Mg(NH3)(6)Cl-2 with LiH. It is found that hydrogen is gradually evolved from the combined system during ball milling. After 24 h of milling, approximate 3.5 mass% of hydrogen, equivalent to 6 mol of H-2 molecules, is released from the Mg(NH3)(6)Cl-2-18LiH mixture. Additional 3.4 mass% of hydrogen is further desorbed from the combined system milled for 24 h with a two-step reaction in heating process. Totally similar to 12 mol of H-2 molecules are librated from the Mg(NH3)(6)Cl-2-18LiH mixture along with the formation and consumption of Mg(NH2)(2) and LiNH2 in the ball milling and subsequent heating process. The resultant products consist of Li2Mg(NH)(2), Li2NH LiH and LiCl after dehydrogenation at 310 degrees C. Further hydrogenation experiment indicates that similar to 6 mol of H-2 molecules are reversibly stored in the Mg(NH3)(6)Cl-2-12LiH mixture. [doi:10.2320/matertrans.MA201013]