Structural characterization of Cu-Ti-based bulk metallic glass by advanced electron microscopy

被引:11
作者
Ishimaru, M [1 ]
Hirotsu, Y
Hata, S
Ma, C
Nishiyama, N
Amiya, K
Inoue, A
机构
[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan
[2] Kyushu Univ, Dept Appl Sci Elect & Mat, Fukuoka 8168580, Japan
[3] R&D Inst Met & Composites Future Ind, Sendai, Miyagi 9808577, Japan
[4] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
关键词
D O I
10.1080/09500830500153776
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The atomistic structure of a high-strength Cu42.5Ti41.5Ni7.5Zr2.5Hf5Si1 bulk metallic glass prepared by copper-mould casting has been characterized by transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM). High-resolution TEM and high-angle annular dark-field observations revealed that crystalline nanoparticles with sizes less than 10 nm are embedded in an amorphous matrix. It was confirmed by energy-dispersive X-ray spectroscopy in combination with STEM that these nanoparticles possess higher copper content than the amorphous matrix. Nanobeam electron diffraction experiments indicated that their crystalline structure is basically face-centred cubic with ordered atomic arrangements.
引用
收藏
页码:125 / 133
页数:9
相关论文
共 22 条
  • [11] Structural relaxation of amorphous silicon carbide
    Ishimaru, M
    Bae, IT
    Hirotsu, Y
    Matsumura, S
    Sickafus, KE
    [J]. PHYSICAL REVIEW LETTERS, 2002, 89 (05)
  • [12] Bulk glass-forming metallic alloys: Science and technology
    Johnson, WL
    [J]. MRS BULLETIN, 1999, 24 (10) : 42 - 56
  • [13] FORMATION OF TI-ZR-CU-NI BULK METALLIC GLASSES
    LIN, XH
    JOHNSON, WL
    [J]. JOURNAL OF APPLIED PHYSICS, 1995, 78 (11) : 6514 - 6519
  • [14] Structural amorphous steels
    Lu, ZP
    Liu, CT
    Thompson, JR
    Porter, WD
    [J]. PHYSICAL REVIEW LETTERS, 2004, 92 (24) : 245503 - 1
  • [15] New ti-based bulk glassy alloys with high glass-forming ability and superior mechanical properties
    Ma, C
    Soejima, H
    Ishihara, S
    Amiya, K
    Nishiyama, N
    Inoue, A
    [J]. MATERIALS TRANSACTIONS, 2004, 45 (11) : 3223 - 3227
  • [16] Massalski T.B., 1990, BINARY ALLOY PHASE D
  • [17] Local structure analysis of Ge-Sb-Te phase change materials using high-resolution electron microscopy and nanobeam diffraction
    Naito, M
    Ishimaru, M
    Hirotsu, Y
    Takashima, M
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 95 (12) : 8130 - 8135
  • [18] Electron diffraction and high-resolution electron microscopy study of an amorphous Pd82Si18 alloy with nanoscale phase separation -: art. no. 094201
    Ohkubo, T
    Hirotsu, Y
    [J]. PHYSICAL REVIEW B, 2003, 67 (09):
  • [19] Ponnambalam V, 2004, J MATER RES, V19, P1320, DOI [10.1557/JMR.2004.0176, 10.1557/jmr.2004.0176]
  • [20] Structure and magnetic property changes of epitaxially grown L10-FePd isolated nanoparticles on annealing
    Sato, K
    Hirotsu, Y
    [J]. JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) : 6291 - 6298