In Situ Spectroelectrochemical Investigation of Electrocatalytic Microbial Biofilms by Surface-Enhanced Resonance Raman Spectroscopy

被引：98

作者：

Millo, Diego ^{[1
]}

Harnisch, Falk ^{[2
]}

Patil, Sunil A. ^{[2
]}

Ly, Hoang K. ^{[1
]}

Schroeder, Uwe ^{[2
]}

Hildebrandt, Peter ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Environm & Sustainable Chem, D-38106 Braunschweig, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 11期

关键词：

cytochromes; electrochemistry; geobacter bacteria; microbial fuel cells; Raman spectroscopy; ANODIC ELECTRON-TRANSFER; CYTOCHROME-C; GEOBACTER; REDUCTION; REDOX; FE(III); CELLS; OXIDE;

D O I：

10.1002/anie.201006046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mixed-culture-derived microbial biofilm, grown on silver electrodes, was studied in vivo with surface-enhanced resonance Raman scattering (SERRS) in combination with cyclic voltammetry. This experimental approach provides unprecedented structural information about the outer membrane cytochromes involved in the direct electron transfer across the bacterium-electrode interface. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：2625 / 2627

页数：3

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