A rhodamine-based fluorescent probe selective for bisulfite anion in aqueous ethanol media

被引:120
作者
Yang, Xiao-Feng [1 ]
Zhao, Minglei [1 ]
Wang, Gang [1 ]
机构
[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Inst Analyt Sci,Dept Chem, Xian 710069, Peoples R China
基金
美国国家科学基金会;
关键词
Fluorescent probe; Bisulfite anion; Rhodamine B; Spirolactam; UNIQUE EXCIMER; CHEMOSENSOR; CHEMODOSIMETER; FLUORIDE; PHOSPHATE; SENSOR; PYROPHOSPHATE; RECEPTORS; CYANIDE; HG2+;
D O I
10.1016/j.snb.2010.09.066
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A rhodamine-based fluorescent probe with an aldehyde functionality as a binding site was developed for the selective detection of bisulfite anion in aqueous ethanol media. The new fluorescent probe showed an excellent selectivity for bisulfite anion over other anions. The bisulfite-induced ring opening of spiro-lactam of the rhodamine moiety resulted in the dual chromo- and fluorogenic observation. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:8 / 13
页数:6
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