Controllable synthesis and growth mechanism of lead free bismuth sodium titanate nanowires

被引:14
作者
Cheng, Cheng [1 ]
Han, Zhuo [1 ]
Liu, Yuzhe [2 ,3 ]
Cheng, Junye [1 ,4 ]
Yang, Junhe [1 ]
Wang, Xianying [1 ]
Zheng, Guangping [1 ,2 ]
机构
[1] Univ Shanghai Sci & Technol, Sch Mat Sci & Engn, Shanghai 200093, Peoples R China
[2] Hong Kong Polytech Univ, Dept Mech Engn, Kowloon, Hong Kong, Peoples R China
[3] Auburn Univ, Dept Mat Engn, Auburn, AL 36849 USA
[4] City Univ Hong Kong, Dept Phys & Mat Sci, Ctr Super Diamond & Adv Films COSDAF, Hong Kong, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
Bismuth sodium titanate; Nanowires; Stirring hydrothermal; Lead-free; Growth mechanisms; ELECTRICAL-PROPERTIES; HYDROTHERMAL SYNTHESIS; PHASE-TRANSITIONS; RAMAN; CERAMICS; SPECTROSCOPY; TEMPERATURE; POWDERS;
D O I
10.1016/j.ceramint.2017.05.115
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Highly uniform lead-free piezoelectric bismuth sodium titanate (Bi0.5Na0.5TiO3, BNT) nanowires were successfully synthesized via a hydrothermal method. Synthesized at a stirring speed range of 300-1000 rpm, the compositions and orientations of BNT nanowires were well controlled. The effects of stirring speeds on the formation of BNT nanoparticles and nanowires in the hydrothermal processes were systematically investigated. The BNT nanowires with a high aspect ratio were proven to be single crystals with [110] growth direction from high-resolution TEM analysis. The mechanism of growth of BNT nanowires out of nanoparticles in the hydrothermal processes was proposed.
引用
收藏
页码:11580 / 11587
页数:8
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