Energy Transfer Between Ce3+and Eu2+in Doped Sr5(PO4)3F Phosphor

被引：14

作者：

Shinde, K. N. ^{[1
]}

Nagpure, I. M. ^{[2
]}

Dhoble, S. J. ^{[3
]}

机构：

[1] NS Sci & Arts Coll, Dept Phys, Bhadrawati 442902, India

[2] Univ Free State, Dept Phys, Bloemfontein, Free State, South Africa

[3] RTM Nagpur Univ, Dept Phys, Nagpur, Maharashtra, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 01期

关键词：

energy transfer; photoluminescence; rare earth ion; UV excitation; XRD; LUMINESCENCE; PHOTOLUMINESCENCE; TRANSITIONS; GLASSES; IONS; EU3+; LAMP;

D O I：

10.1080/15533174.2010.538021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sr5(PO4)3F phosphor doped with Eu[image omitted] and Ce[image omitted] ion were prepared by combustion synthesis. Under UV excitation (254 nm) Sr5(PO4)3F:Ce exhibits Ce[image omitted] UV emission (355 nm) and under 354 nm, Sr5(PO4)3F:Eu exhibits Eu[image omitted] emission (440 nm). The aim of this article is to report energy transfer mechanism between Ce[image omitted]Eu[image omitted] ion in Sr5(PO4)3F:Ce,Eu phosphors, where Ce ion act as sensitizer and Eu act as activator. Ce emission energy band is in resonance with Eu excitation energy band. Their structures properties and photoluminescence spectra were systemically studied. This article includes synthesis of phosphor, XRD, EDS, SEM pattern of host lattice, photoluminescence behavior, and energy transfer mechanism between the two rare earth ions.

引用

页码：107 / 113

页数：7

共 29 条

[11] Synthesis of lamp phosphors: facile combustion approach [J].

Ekambaram, S ;

Patil, KC ;

Maaza, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 393 (1-2) :81-92

[12] Structural investigation of Eu2+ emissions from alkaline earth zirconium phosphate [J].

Hirayama, Masaaki ;

Sonoyama, Noriyuki ;

Yamada, Atsuo ;

Kanno, Ryoji .

JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (04) :730-735

[13] Composition-dependent loss of phosphorus in the formation of transition-metal phosphate glasses [J].

Khattak, GD ;

Khawaja, EE ;

Wenger, LE ;

Thompson, DJ ;

Salim, MA ;

Hallak, AB ;

Daous, MA .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 194 (1-2) :1-12

[14] LUMINESCENCE OF CE-3+-SENSITIZED AND DY-3+-ACTIVATED ALUMINOBORATES, CA3AL6B8O24, BA3AL6B8O24 [J].

KUTTY, TRN .

MATERIALS RESEARCH BULLETIN, 1990, 25 (04) :485-493

[15] Synthesis of a new NASICON-type blue luminescent material [J].

Masui, Toshiyuki ;

Koyabu, Kazuhiko ;

Tamura, Shinji ;

Imanaka, Nobuhito .

JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 418 (1-2) :73-76

[16] Spectral hole burning in the 4f-5d transition of Ce3+ in LuPO4 and YPO4 [J].

Meltzer, RS ;

Feofilov, SP .

JOURNAL OF LUMINESCENCE, 2003, 102 :151-155

[17] Combustion synthesis and luminescence investigation of Na3Al2(PO4)3:RE (RE = Ce3+, Eu3+ and Mn2+) phosphor [J].

Nagpure, I. M. ;

Shinde, K. N. ;

Kumar, Vinay ;

Ntwaeaborwa, O. M. ;

Dhoble, S. J. ;

Swart, H. C. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 492 (1-2) :384-388

[18] Photoluminescence and thermoluminescence characterization of Eu3+- and Dy3+-activated Ca3(PO4)2 phosphor [J].

Nagpure, I. M. ;

Saha, Subhajit ;

Dhoble, S. J. .

JOURNAL OF LUMINESCENCE, 2009, 129 (09) :898-905

[19] Photoluminescence characterization of Dy3+ and Eu2+ ion in M5(PO4)3F (M = Ba, Sr, Ca) phosphors [J].

Nagpure, I. M. ;

Shinde, K. N. ;

Dhoble, S. J. ;

Kumar, Animesh .

JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) :632-638

[20] Crystallization region, crystal growth, and phase transitions of KNd(PO3)4 [J].

Parreu, I ;

Solé, R ;

Gavaldà, J ;

Massons, J ;

Díaz, F ;

Aguiló, M .

CHEMISTRY OF MATERIALS, 2003, 15 (26) :5059-5064

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