Heterometal expansion of oxozirconium carboxylate clusters

被引:33
作者
Malaestean, Iurii L. [1 ]
Speldrich, Manfred [1 ]
Ellern, Arkady [2 ]
Baca, Svetlana G. [3 ]
Koegerler, Paul [1 ,2 ]
机构
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany
[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
[3] ASM, Inst Chem, Kishinev 2028, Moldova
关键词
MOLECULAR SPINTRONICS; BUILDING-BLOCKS; SYSTEMS; ZR6O4(OH)(4)(OOCR)(12); MAGNETS; CORE;
D O I
10.1039/c0dt01136c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Although representing a 'thermodynamic sink', the octahedral oxozirconium {Zr6O4(OH)(4)} cluster structure can be magnetically functionalized by up to six 3d metal cations with a combination of flexible aminoalkoxide and carboxylate ligands.
引用
收藏
页码:331 / 333
页数:3
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