A high pressure, high temperature infrared study of CO hydrogenation over Rh/ZrO2

被引：18

作者：

Anderson, JA

Khader, MM

机构：

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 105卷 / 03期

关键词：

carbon monoxide; hydrogenation; infrared spectroscopy; rhodium; zirconia; supported catalysts;

D O I：

10.1016/1381-1169(95)00247-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Rh/ZrO2 catalyst has been studied in the hydrogenation of CO in an in situ IR cell operating at high temperature and pressure, and using FTIR to follow the formation of surface and gas phase species as a function of reaction time. The reaction between CO and hydrogen was studied by varying the catalyst reduction temperature, reaction temperature, total pressure and hydrogen/CO ratio. Surface species identified were carbonyls on the rhodium surface, formates, carbonates and hydrocarbons. The relationship between adsorbed carbonate and formate is discussed in detail.

引用

页码：175 / 183

页数：9

共 31 条

[11] MECHANISTIC ASPECTS OF THE FORMATION OF HYDROCARBONS AND ALCOHOLS FROM CO HYDROGENATION [J].

HINDERMANN, JP ;

HUTCHINGS, GJ ;

KIENNEMANN, A .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1993, 35 (01) :1-127

[12] HYDROGEN SPILLOVER PHENOMENA ON PT/ZRO2 [J].

HOANG, DL ;

BERNDT, H ;

LIESKE, H .

CATALYSIS LETTERS, 1995, 31 (2-3) :165-172

[13] CATALYSIS BY SUPPORTED METAL CRYSTALLITES FROM CARBONYL CLUSTERS .1. CATALYTIC METHANOL SYNTHESIS UNDER MILD CONDITIONS OVER SUPPORTED RHODIUM, PLATINUM, AND IRIDIUM CRYSTALLITES PREPARED FROM RH, PT, AND IR CARBONYL CLUSTER COMPOUNDS DEPOSITED ON ZNO AND MGO [J].

ICHIKAWA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (08) :2268-2272

[14] CATALYSIS BY SUPPORTED METAL CRYSTALLITES FROM CARBONYL CLUSTERS .2. CATALYTIC ETHANOL SYNTHESIS FROM CO AND H-2 UNDER ATMOSPHERIC-PRESSURE OVER SUPPORTED RHODIUM CRYSTALLITES PREPARED FROM RH CARBONYL CLUSTERS DEPOSITED ON TIO2, ZRO2, AND LA2O3 [J].

ICHIKAWA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (08) :2273-2277

[15]

ICHIKAWA M, 1981, J MOL CATAL, V11, P167, DOI 10.1007/BF01210391

[16] THE ROLE OF THE SUPPORT IN CO HYDROGENATION SELECTIVITY OF SUPPORTED RHODIUM [J].

KATZER, JR ;

SLEIGHT, AW ;

GAJARDO, P ;

MICHEL, JB ;

GLEASON, EF ;

MCMILLAN, S .

FARADAY DISCUSSIONS, 1981, 72 :121-133

[17]

Little L. H., 1966, Infrared Spectra of Adsorbed Species

[18] AN INSITU HIGH-PRESSURE FT-IR STUDY OF CO2/H-2 INTERACTIONS WITH MODEL ZNO/SIO2, CU/SIO2 AND CU/ZNO/SIO2 METHANOL SYNTHESIS CATALYSTS [J].

MILLAR, GJ ;

ROCHESTER, CH ;

WAUGH, KC .

CATALYSIS LETTERS, 1992, 14 (3-4) :289-295

[19]

MILLAR GJ, 1991, MOL PHYS, V4, P833

[20]

Nakamoto K., 2009, Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part A: Theory and Applications in Inorganic Chemistry, V6th ed.

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