Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions

被引：269

作者：

Brand, Jonathan P. ^{[1
]}

Gonzalez, Davinia Fernandez ^{[1
]}

Nicolai, Stefano ^{[1
]}

Waser, Jerome ^{[1
]}

机构：

[1] EPFL SB ISIC LCSO, Ecole Polytech Fed Lausanne, BCH 4306, Lab Catalysis & Organ Synth, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 01期

基金：

瑞士国家科学基金会;

关键词：

HYDROXYLATIVE PHENOL DEAROMATIZATION; MILD ELECTROPHILIC TRIFLUOROMETHYLATION; GACL3-CATALYZED ORTHO-ETHYNYLATION; CATALYZED DIRECT ALKYNYLATION; IODOXYBENZOIC ACID IBX; ORGANIC-SYNTHESIS; POLYVALENT IODINE; SYNTHETIC UTILITY; OXIDATIVE DEAROMATIZATION; TERT-BUTYLPEROXYIODANES;

D O I：

10.1039/c0cc02265a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the last decades, hypervalent iodine reagents have raised from chemical curiosities to mainstream reagents in organic synthesis. The use of benziodoxole-derived reagents has been especially successful in oxidation methods, whereas non-cyclic iodinanes have been used both for oxidation and atom-transfer reactions. On the other hand, the exceptional properties of benziodoxole reagents for atom-transfer reactions have only started to attract the attention of the synthetic community more recently. In this review, progress in the use of these compounds for C-X and C-C bond formations will be presented. In particular, recent breakthroughs in trifluoromethylation and alkynylation reactions have been realized since 2006 based on benziodoxole-derived reagents and these results are the main focus of this article.

引用

页码：102 / 115

页数：14

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