Chemicals from biomass: Etherification of 5-hydroxymethyl-2-furfural (HMF) into 5,5′(oxy-bis(methylene))bis-2-furfural (OBMF) with solid catalysts

被引:73
|
作者
Casanova, O. [1 ]
Iborra, S. [1 ]
Corma, A. [1 ]
机构
[1] Univ Politecn Valencia, Inst Tecnol Quim UPV CSIC, Valencia 46022, Spain
关键词
Catalysis; OBMF; 5-Hydroxymethyl-2-furaldehyde; Zeolite; MCM-41; BAEYER-VILLIGER OXIDATIONS; WATER-RESISTANT; PHASE SYNTHESIS; ZEOLITE; BETA; DEHYDRATION; METHANOL; ISOBUTENE; MECHANISM; ALCOHOLS;
D O I
10.1016/j.jcat.2010.08.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Starting from 5-hydroxymethyl-2-furaldehyde (HMF), it has been possible to produce 5,5'-oxy(bismethylene)-2-furaldehyde (OBMF), which is an interesting prepolymer and antiviral precursor, using Lewis and Bronsted solid acid catalysts. Structured micro- and mesoporous aluminosilicates are active and selective, but Al-MCM-41 displays the best performance owing to smaller diffusion constraints. The yield obtained is higher than with homogeneous acid catalysts. Metal-substituted zeolites and mesoporous materials bearing Lewis acidity are also active and selective catalysts for the above reaction. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码:236 / 242
页数:7
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