Chemicals from biomass: Etherification of 5-hydroxymethyl-2-furfural (HMF) into 5,5′(oxy-bis(methylene))bis-2-furfural (OBMF) with solid catalysts

被引：73

作者：

Casanova, O. ^{[1
]}

Iborra, S. ^{[1
]}

Corma, A. ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim UPV CSIC, Valencia 46022, Spain

来源：

JOURNAL OF CATALYSIS | 2010年 / 275卷 / 02期

关键词：

Catalysis; OBMF; 5-Hydroxymethyl-2-furaldehyde; Zeolite; MCM-41; BAEYER-VILLIGER OXIDATIONS; WATER-RESISTANT; PHASE SYNTHESIS; ZEOLITE; BETA; DEHYDRATION; METHANOL; ISOBUTENE; MECHANISM; ALCOHOLS;

D O I：

10.1016/j.jcat.2010.08.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Starting from 5-hydroxymethyl-2-furaldehyde (HMF), it has been possible to produce 5,5'-oxy(bismethylene)-2-furaldehyde (OBMF), which is an interesting prepolymer and antiviral precursor, using Lewis and Bronsted solid acid catalysts. Structured micro- and mesoporous aluminosilicates are active and selective, but Al-MCM-41 displays the best performance owing to smaller diffusion constraints. The yield obtained is higher than with homogeneous acid catalysts. Metal-substituted zeolites and mesoporous materials bearing Lewis acidity are also active and selective catalysts for the above reaction. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：236 / 242

页数：7

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