Synthesis of (2-iminomethyl)pyridine Moiety Supported on Hydroxyapatite-encapsulated-γ-Fe2O3 as an Inorganic-organic Hybrid Magnetic Nanocatalyst for the Synthesis of Thiazole Derivatives under Ultrasonic Irradiation

被引：11

作者：

Ahmadiazar, Mohammad ^{[1
]}

Mamaghani, Manouchehr ^{[1
]}

机构：

[1] Univ Guilan, Fac Sci, Dept Chem, POB 41335-1914, Rasht, Iran

来源：

CURRENT ORGANIC CHEMISTRY | 2018年 / 22卷 / 13期

关键词：

gamma-Fe2O3@HAp; thiazole; rhodanine; thiazolone; ultrasonic irradiation; multicomponent reaction; EXPEDITIOUS SYNTHESIS; SELECTIVE OXIDATION; LEWIS-ACIDS; NANOPARTICLES; INHIBITORS; EFFICIENT; CATALYSTS; SCIENCE; IDENTIFICATION; KETONES;

D O I：

10.2174/1385272822666180322121544

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel pyridine base modified core-shell (gamma-Fe2O3@Hap (Hap: Hydroxyapatite)) inorganic-organic hybrid magnetic nanocatalyst has been introduced. The catalyst was fully characterized by spectroscopic analyses (FT-IR, FESEM, EDX, XRD) and its efficiency evaluated as a basic catalyst in one-pot multicomponent reaction of aryl aldehydes, rhodanine and piperidine under ultrasonic irradiation to obtain thiazole derivatives. This green, fast and straightforward protocol produced the products in short reaction times (14-40 min) and high to excellent yields (75-95%).

引用

页码：1326 / 1334

页数：9

共 61 条

[1] A collaborative effect between gold and a support induces the selective oxidation of alcohols [J].

Abad, A ;

Concepción, P ;

Corma, A ;

García, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) :4066-4069

[2] Regioselective base-induced condensations of acrylic acid derivatives [J].

Abdel-Ghani, E .

JOURNAL OF CHEMICAL RESEARCH, 1999, (03) :174-175A

[3] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[4] Three-component one-pot synthetic route to 2-amino-5-alkylidene-thiazol-4-ones [J].

Anderluh, Marko ;

Jukic, Marko ;

Petric, Rok .

TETRAHEDRON, 2009, 65 (01) :344-350

[5] Synthesis and cardiotonic activity of imidazo[2,1-b]thiazoles bearing a lactam ring [J].

Andreani, A ;

Rambaldi, M ;

Leoni, A ;

Locatelli, A ;

Bossa, R ;

Chiericozzi, M ;

Galatulas, I ;

Salvatore, G .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 1996, 31 (05) :383-387

[6] SYNTHESIS OF LACTAMS WITH POTENTIAL CARDIOTONIC ACTIVITY [J].

ANDREANI, A ;

RAMBALDI, M ;

LOCATELLI, A ;

LEONI, A ;

BOSSA, R ;

CHIERICOZZI, M ;

GALATULAS, I ;

SALVATORE, G .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 1993, 28 (10) :825-829

[7] An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water [J].

Baleizao, C ;

Corma, A ;

García, H ;

Leyva, A .

CHEMICAL COMMUNICATIONS, 2003, (05) :606-607

[8] A practical access to novel 2-amino-5-arylidene-1,3-thiazol-4(5H)-ones via sulfur/nitrogen displacement under solvent-free microwave irradiation [J].

Bourahla, Khadidja ;

Derdour, Aicha ;

Rahmouni, Mustapha ;

Carreaux, Francois ;

Bazureau, Jean Pierre .

TETRAHEDRON LETTERS, 2007, 48 (33) :5785-5789

[9] Lewis acids as catalysts in oxidation reactions:: From homogeneous to heterogeneous systems [J].

Corma, A ;

García, H .

CHEMICAL REVIEWS, 2002, 102 (10) :3837-3892

[10] Lewis acids:: From conventional homogeneous to green homogeneous and heterogeneous catalysis [J].

Corma, A ;

García, H .

CHEMICAL REVIEWS, 2003, 103 (11) :4307-4365

← 1 2 3 4 5 6 7 →