Polyvinylidene fluoride: A multifunctional polymer in supercapacitor applications

被引:76
作者
Rajeevan, Sreelakshmi [1 ,2 ]
John, Sam [3 ]
George, Soney C. [1 ]
机构
[1] Amal Jyothi Engn Coll, Ctr Nanosci & Technol, Koovapally 686518, Kerala, India
[2] APJ Abdul Kalam Technol Univ, CET Campus, Thiruvananthapuram 695016, Kerala, India
[3] St Berchmans Coll, Changanassery 686101, Kerala, India
关键词
Supercapacitor; PVDF; Electrolyte; Binder; Separator; Charge carriers; ALL-SOLID-STATE; NANOCOMPOSITE MEMBRANE ELECTROLYTE; HIGH-PERFORMANCE; POLY(VINYLIDENE FLUORIDE); PVDF-HFP; GEL POLYMER; ACTIVATED CARBON; GRAPHENE OXIDE; HIGH-POWER; ELECTROCHEMICAL CHARACTERIZATION;
D O I
10.1016/j.jpowsour.2021.230037
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The rising energy consumption in today's world need electrochemical devices with excellent energy storing efficiency. Supercapacitors are considered as incredible energy-storing devices due to high power density, longevity, exceptional charge/discharge cycling stability, and low cost. The electrochemical performance of the supercapacitors absolutely relies upon the choice of its establishing parts like electrodes, binder, separator, electrolyte, and current collector; and its manufacture strategy. The part of polymers in this field is inescapable and has a background marked by many years. This review deliberately extends the part of polyvinylidene fluoride (PVDF); its copolymer and nanocomposites as a binder, separator, electrolyte, and piezoelectric generator in the development of supercapacitors. Polyvinylidene fluoride is a semi-crystalline polymer and the second-biggest fluoropolymer underway. It displays great mechanical properties, high dielectric consistent, wettability, and excellent thermal and chemical strength. Today, PVDF is quite possibly the most requesting polymers because of its self-polarizing capacity under the electric field. The piezoelectric, pyroelectric, and ferroelectric properties of PVDF pulls into the consideration of researchers and specialists who are working in the development of self-charging supercapacitors and other energy reaping and storing gadgets. This review succinctly uncovers the future viewpoint for the advancement of PVDF-based self-powering electronic gadgets.
引用
收藏
页数:19
相关论文
共 162 条
[111]   Two steps synthesis approach of MnO2/graphene nanoplates/graphite composite electrode for supercapacitor application [J].
Rashed, A. E. ;
El-Moneim, A. A. .
MATERIALS TODAY ENERGY, 2017, 3 :24-31
[112]  
Rohmawati L., 2018, CAPACITANCE STABILIT, P512
[113]   Properties and Applications of the β Phase Poly(vinylidene fluoride) [J].
Ruan, Liuxia ;
Yao, Xiannian ;
Chang, Yufang ;
Zhou, Lianqun ;
Qin, Gaowu ;
Zhang, Xianmin .
POLYMERS, 2018, 10 (03)
[114]   High performance self-charging supercapacitors using a porous PVDF-ionic liquid electrolyte sandwiched between two-dimensional graphene electrodes [J].
Sahoo, Surjit ;
Krishnamoorthy, Karthikeyan ;
Pazhamalai, Parthiban ;
Mariappan, Vimal Kumar ;
Manoharan, Sindhuja ;
Kim, Sang-Jae .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (38) :21693-21703
[115]  
Sajkiewicz P., 1999, EUR POLYM J, V7
[116]   Plasticized microporous poly(vinylidene fluoride) separators for lithium-ion batteries. III. Gel properties and irreversible modifications of poly(vinylidene fluoride) membranes under swelling in liquid electrolytes [J].
Saunier, J ;
Alloin, F ;
Sanchez, JY ;
Maniguet, L .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (12) :2308-2317
[117]  
Senthilkumar V, COMP SUPERCAPACITANC, P26
[118]   Development of ion conducting polymer gel electrolyte membranes based on polymer PVdF-HFP, BMIMTFSI ionic liquid and the Li-salt with improved electrical, thermal and structural properties [J].
Shalu ;
Singh, Varun Kumar ;
Singh, Rajendra Kumar .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (28) :7305-7318
[119]   Design and Mechanisms of Asymmetric Supercapacitors [J].
Shao, Yuanlong ;
El-Kady, Maher F. ;
Sun, Jingyu ;
Li, Yaogang ;
Zhang, Qinghong ;
Zhu, Meifang ;
Wang, Hongzhi ;
Dunn, Bruce ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2018, 118 (18) :9233-9280
[120]   Swift heavy ions irradiated PVDF/BaTiO3 film as a separator for supercapacitors [J].
Sharma, Mandakini ;
Gaur, Anurag ;
Quamara, J. K. .
SOLID STATE IONICS, 2020, 352