First Total Synthesis of Pandamarine

被引：34

作者：

Kalaitzakis, Dimitris ^{[1
]}

Noutsias, Dimitris ^{[1
]}

Vassilikogiannakis, Georgios ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 14期

基金：

欧洲研究理事会;

关键词：

AUS SCHIZOZYGIA CAFFAEOIDES; ONE-POT SYNTHESIS; PANDANUS-AMARYLLIFOLIUS; SINGLET-OXYGEN; SIMPLE FURANS; INDOLE ALKALOIDS; HAPLOPHYTINE;

D O I：

10.1021/acs.orglett.5b01693

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first total synthesis of pandamarine, an alkaloid isolated from Pandanus amaryllifolius is reported. The key step of this extremely short (six steps in total) and protecting group-free synthesis is a highly efficient cascade reaction sequence initiated by the photooxidation of an easily accessible, and symmetric difuran precursor.

引用

页码：3596 / 3599

页数：4

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