Growth and characterization of new nonlinear optical L-threonium acetate single crystals

被引：0
作者：
Kumar, GR
Raja, SG
Mohan, R
Jayavel, R [1 ]
机构：
[1] Anna Univ, Ctr Crystal Growth, Madras 600025, Tamil Nadu, India
[2] Presidency Coll, Dept Phys, Madras 600005, Tamil Nadu, India
来源：
JOURNAL OF CRYSTAL GROWTH | 2005年 / 283卷 / 1-2期
关键词：
growth from solution; nonlinear optical materials;
D O I：
10.1016/j.jcrusgro.2005.04.103
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
New nonlinear optical (NLO) single crystal of (L)-threonium acetate was grown by slow evaporation and temperature lowering methods from aqueous solution. The grown crystals were characterized by X-ray diffractometry (XRD), UV-vis-NIR, Fourier Transform infrared (FTIR) and mass spectral analysis. XRD and FTIR studies reveal that the (L)-threonine: acetic acid stoichiornetry is equal to 1:1. Transmittance spectrum of the crystal shows complete transparency even in the NIR region. Mass spectrometry of the crystalline compound confirms the molecular weight of the title crystal. The NLO property of the grown crystal has been confirmed by Kurtz-powder second harmonic generation (SHG) test and its SHG efficiency was found as d(eff) = 1.14 d(eff) (KDP). (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：193 / 197
页数：5
相关论文
共 12 条
[1]   Solution growth of a novel nonlinear optical material: L-histidine tetrafluoroborate [J].
Aggarwal, MD ;
Choi, J ;
Wang, WS ;
Bhat, K ;
Lal, RB ;
Shields, AD ;
Penn, BG ;
Frazier, DO .
JOURNAL OF CRYSTAL GROWTH, 1999, 204 (1-2) :179-182
[2]  
BABU DJ, 2003, THESIS U MADRAS INDI
[3]   GROWTH AND DEFECT CHARACTERIZATION OF L-ARGININE PHOSPHATE MONOHYDRATE [J].
DHANARAJ, G ;
SHRIPATHI, T ;
BHAT, HL .
JOURNAL OF CRYSTAL GROWTH, 1991, 113 (3-4) :456-464
[4]   Optical materials for short wavelength generation [J].
Egger, P ;
Hulliger, J .
COORDINATION CHEMISTRY REVIEWS, 1999, 183 :101-115
[5]   Growth, structural, optical and thermal studies of non-linear optical L-threonine single crystals [J].
Kumar, GR ;
Raj, SG ;
Sankar, R ;
Mohan, R ;
Pandi, S ;
Jayavel, R .
JOURNAL OF CRYSTAL GROWTH, 2004, 267 (1-2) :213-217
[6]  
KUMAR RM, IN PRESS J CRYSTAL G
[7]   A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].
KURTZ, SK ;
PERRY, TT .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+
[8]   L-HISTIDINE TETRAFLUOROBORATE - A SOLUTION-GROWN SEMIORGANIC CRYSTAL FOR NONLINEAR FREQUENCY-CONVERSION [J].
MARCY, HO ;
ROSKER, MT ;
WARREN, LF ;
CUNNINGHAM, PH ;
THOMAS, CA ;
DELOACH, LA ;
VELSKO, SP ;
EBBERS, CA ;
LIAO, JH ;
KANATZIDIS, MG .
OPTICS LETTERS, 1995, 20 (03) :252-254
[9]   SYNTHESIS AND CHARACTERIZATION OF CHEMICAL ANALOGS OF L-ARGININE PHOSPHATE [J].
MONACO, SB ;
DAVIS, LE ;
VELSKO, SP ;
WANG, FT ;
EIMERL, D ;
ZALKIN, A .
JOURNAL OF CRYSTAL GROWTH, 1987, 85 (1-2) :252-255
[10]  
Razzetti C, 2002, CRYST RES TECHNOL, V37, P456, DOI 10.1002/1521-4079(200205)37:5<456::AID-CRAT456>3.0.CO
12