Sulfonated polyether ether ketone based composite polymer electrolyte membranes

被引：151
作者：
Mikhailenko, SD [1 ]
Zaidi, SMJ [1 ]
Kaliaguine, S [1 ]
机构：
[1] Univ Laval, Dept Chem Engn, Quebec City, PQ G1K 7P4, Canada
来源：
CATALYSIS TODAY | 2001年 / 67卷 / 1-3期
关键词：
composite membranes; electrochemistry; polyether ether ketone (PEEK); boron phosphate;
D O I：
10.1016/S0920-5861(01)00290-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Electrochemical properties of a series of composite membranes prepared by incorporation of boron phosphate into polymeric matrix of sulfonated PEEK were studied. The conductivity of the composites was found to exceed largely that of pure SPEEK polymer. It was however lower than predicted by the effective medium theory for these mixtures. This is associated to the formation of a capillary pore system in the membranes. Despite the developed porosity the composite membranes proved to be mechanically strong and not affected by long term storage in water. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：225 / 236
页数：12
相关论文
共 19 条
  • [1] SOLUBILITY AND PROPERTIES OF A POLY(ARYL ETHER KETONE) IN STRONG ACIDS
    BISHOP, MT
    KARASZ, FE
    RUSSO, PS
    LANGLEY, KH
    [J]. MACROMOLECULES, 1985, 18 (01) : 86 - 93
  • [2] Bonnet B, 2000, J NEW MAT ELECT SYST, V3, P87
  • [3] A SULFONATED POLY(ARYL ETHER KETONE)
    JIN, XG
    BISHOP, MT
    ELLIS, TS
    KARASZ, FE
    [J]. BRITISH POLYMER JOURNAL, 1985, 17 (01): : 4 - 10
  • [4] JONES DJ, 1999, 3 INT S NEW MAT FUEL, P248
  • [5] KERRES J, 1999, 3 INT S NEW MAT EL S, P230
  • [6] Proton-conducting polymers derived from poly(ether-etherketone) and poly(4-phenoxybenzoyl-1,4-phenylene)
    Kobayashi, T
    Rikukawa, M
    Sanui, K
    Ogata, N
    [J]. SOLID STATE IONICS, 1998, 106 (3-4) : 219 - 225
  • [7] Proton conductivity: Materials and applications
    Kreuer, KD
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (03) : 610 - 641
  • [8] Mikhailenko SD, 2000, J POLYM SCI POL PHYS, V38, P1386, DOI 10.1002/(SICI)1099-0488(20000515)38:10<1386::AID-POLB160>3.3.CO
  • [9] 2-W
  • [10] Electrical conductivity of boron orthophosphate in presence of water
    Mikhailenko, SD
    Zaidi, J
    Kaliaguine, S
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (11): : 1613 - 1618
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